Trichloro-bridged diruthenium (III,III) complexes: X-ray isomorphous structures of [Ph3X=O center dot center dot center dot H center dot center dot center dot O=XPh3][Ru2Cl7(XPh3)(2)]center dot 0.5(CH2Cl2)(H2O)(X = As or P)

dc.contributorUniversidade Federal de São Carlos (UFSCar)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:22:20Z
dc.date.available2014-05-20T15:22:20Z
dc.date.created2014-05-20T15:22:20Z
dc.date.issued2002-01-01
dc.identifierTransition Metal Chemistry. Dordrecht: Kluwer Academic Publ, v. 27, n. 1, p. 110-114, 2002.
dc.identifier0340-4285
dc.identifierhttp://hdl.handle.net/11449/33334
dc.identifier10.1023/A:1013471818192
dc.identifierWOS:000173087200020
dc.description.abstractThe triply chloro-bridged binuclear complexes [Ph3X=O...H...O=XPh3][Ru2Cl7(XPh3)(2)].0.5(CH2Cl2) (H2O) (X = As or P) were obtained from [RuCl3(XPh3)(2)DMA].DMA (DMA = dimethylacetamide) CH2Cl2/Et2O solution. The structures were characterized by X-ray diffraction studies. The complexes are formed from two Ru atoms bridged by three chloride anions. The two ruthenium atoms are also coordinated to two non-bridging Cl atoms and an AsPh3 or PPh3 ligand respectively. As an interesting feature, the cations of these complexes are protons, trapped in a very short hydrogen bond between two triphenylarsine or triphenylphosphine oxide molecules.
dc.languageeng
dc.publisherKluwer Academic Publ
dc.relationTransition Metal Chemistry
dc.relation1.261
dc.relation0,306
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.titleTrichloro-bridged diruthenium (III,III) complexes: X-ray isomorphous structures of [Ph3X=O center dot center dot center dot H center dot center dot center dot O=XPh3][Ru2Cl7(XPh3)(2)]center dot 0.5(CH2Cl2)(H2O)(X = As or P)
dc.typeArtículos de revistas


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