Cycloaddition reaction of the azido-bridged cyclometallated complex [Pd(dmba)N-3](2) with CS2. Crystal and molecular structure of DI(mu, N,S-1,2,3,4-thiatriazole-5-thiolate) bis[(N,N-dimethylbenzyl-amine-C-2,N)palladium(II)]

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:21:54Z
dc.date.available2014-05-20T15:21:54Z
dc.date.created2014-05-20T15:21:54Z
dc.date.issued1999-01-01
dc.identifierJournal of Coordination Chemistry. Reading: Gordon Breach Sci Publ Ltd, v. 48, n. 4, p. 521-528, 1999.
dc.identifier0095-8972
dc.identifierhttp://hdl.handle.net/11449/32979
dc.identifier10.1080/00958979908023592
dc.identifierWOS:000082689300016
dc.description.abstractThe 1,3-dipolar cycloaddition of carbon disulfide to the coordinated azide in the cyclometallated compound [Pd(dmba)(N-3)](2) (1), dmba = N,N-dimethylbenzylamine, was investigated. The compound obtained di(mu, N,S-1,2,3,4-thiatriazole-5-thiolate)-bis[(N,N-dimethylbenzylamine-C-2,N)palladium(II)] (2), was characterized by IR spectroscopy and X-ray diffraction. Complex (2) is dimeric with the two [Pd(N,N-dimethylbenzylamine)] moieties being connected by the two vicinal bridging N,S-1,2,3,4-thiatriazole-5-thiolate anions in a square-planar coordination for the palladium atoms.
dc.languageeng
dc.publisherGordon Breach Sci Publ Ltd
dc.relationJournal of Coordination Chemistry
dc.relation1.703
dc.relation0,371
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectcycloaddition
dc.subjectpalladium
dc.subjectazido
dc.subjectcarbon disulfide
dc.subjectinfrared spectroscopy
dc.subjectX-ray diffraction
dc.titleCycloaddition reaction of the azido-bridged cyclometallated complex [Pd(dmba)N-3](2) with CS2. Crystal and molecular structure of DI(mu, N,S-1,2,3,4-thiatriazole-5-thiolate) bis[(N,N-dimethylbenzyl-amine-C-2,N)palladium(II)]
dc.typeArtículos de revistas


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