A comparative study of hydrosilane compounds as cocatalysts in the metathesis of 1-hexene

dc.contributorUniversidade Federal do Rio Grande do Sul (UFRGS)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:21:36Z
dc.date.available2014-05-20T15:21:36Z
dc.date.created2014-05-20T15:21:36Z
dc.date.issued1998-12-21
dc.identifierJournal of Molecular Catalysis A-chemical. Amsterdam: Elsevier B.V., v. 136, n. 3, p. 213-217, 1998.
dc.identifier1381-1169
dc.identifierhttp://hdl.handle.net/11449/32729
dc.identifier10.1016/S1381-1169(98)00076-4
dc.identifierWOS:000077201700001
dc.description.abstractThe selectivity of I-hexene metathesis using WCI6 as catalyst was evaluated with a series of hydrosilane-compounds as cocatalysts: Ph3SiH, Ph2SiH2, PhSiH3 and polymethylhydrosiloxane (PMHS). The metathesis reaction is favored by the addition of promoters. When in the presence of WCl4(OAr)(2), OAr = 2,6-dichlorophenoxide, 2,6-difluorophenoxide, olefin metathesis occurs with good selectivity without the use of promoters. (C) 1998 Elsevier B.V. B.V. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationJournal of Molecular Catalysis A: Chemical
dc.relation4.397
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjecttungsten catalyst
dc.subjecthydrosilane cocatalysts
dc.subject1-hexene metathesis
dc.titleA comparative study of hydrosilane compounds as cocatalysts in the metathesis of 1-hexene
dc.typeArtículos de revistas


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