Supramolecular assemblies of cis-palladium complexes dominated by C-H center dot center dot center dot Cl interactions

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:20:25Z
dc.date.available2014-05-20T15:20:25Z
dc.date.created2014-05-20T15:20:25Z
dc.date.issued2006-05-01
dc.identifierInorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 9, n. 5, p. 493-496, 2006.
dc.identifier1387-7003
dc.identifierhttp://hdl.handle.net/11449/31730
dc.identifier10.1016/j.inoche.2006.02.012
dc.identifierWOS:000237634800016
dc.description.abstractTwo cis-related palladium(II) complexes [PdCl(2)(PPh(3))(tu)] (1) and [PdCl(2)(tmen)] (2) {PPh(3) = triphenylphosphine, tu = thiourea, tmen = N,N,N,N-tetramethylethylenediamine} have been synthesized and characterized by elemental analysis, IR and NMR spectroscopies, and single crystal X-ray diffraction. In 1, N-H center dot center dot center dot Cl hydrogen bonds are responsible for the formation of a dimer which connects to an adjacent one through weak C-H center dot center dot center dot Cl interactions, yielding 1D tapes. The crystal packing of compound 2 consists of zigzag ribbons of [PdCl(2)(tmen)] self-assembled by C-H center dot center dot center dot Cl hydrogen bonds which also holds the chains together, giving rise to a 2D layered structure. (C) 2006 Elsevier B.V. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationInorganic Chemistry Communications
dc.relation1.810
dc.relation0,430
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectsupramolecular chemistry
dc.subjectC-H center dot center dot center dot Cl hydrogen bonds
dc.subjectpalladium(II)
dc.subjectself-assembly
dc.titleSupramolecular assemblies of cis-palladium complexes dominated by C-H center dot center dot center dot Cl interactions
dc.typeArtículos de revistas


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