Self-assembly of metallosupramolecules directed by (N-H)(2)center dot center dot center dot SCN-M (M = Co, Ni), C-H center dot center dot center dot pi and pi-pi synthons

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:20:21Z
dc.date.available2014-05-20T15:20:21Z
dc.date.created2014-05-20T15:20:21Z
dc.date.issued2006-02-06
dc.identifierJournal of Molecular Structure. Amsterdam: Elsevier B.V., v. 783, n. 1-3, p. 161-167, 2006.
dc.identifier0022-2860
dc.identifierhttp://hdl.handle.net/11449/31675
dc.identifier10.1016/j.molstruc.2005.08.031
dc.identifierWOS:000235589000019
dc.identifier3300223970814448
dc.identifier8534138813417161
dc.identifier0000-0003-1574-681X
dc.description.abstractThis work deals with the synthesis, spectroscopic and structural investigation of pyrazolyl complexes of the type trans-[M(NCS)(2)(HPz)(4)] {M=Co (1), Ni (2); HPz=pyrazole}. Single crystal X-ray studies on 1 and 2 reveal the formation of similar supramolecular arrangements derived from self-assembly of monomers linked together through intermolecular N-H center dot center dot center dot SCN hydrogen bonds, C-H center dot center dot center dot pi interactions and pi-pi stacking. (c) 2005 Elsevier B.V. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationJournal of Molecular Structure
dc.relation2.011
dc.relation0,409
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectCo(II) and Ni(II) pyrazolyl complexes
dc.subjectthiocyanate
dc.subjectself-assembly
dc.subjecthydrogen bonding
dc.subjectsupramolecular synthon
dc.titleSelf-assembly of metallosupramolecules directed by (N-H)(2)center dot center dot center dot SCN-M (M = Co, Ni), C-H center dot center dot center dot pi and pi-pi synthons
dc.typeArtículos de revistas


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