Synthesis, Infrared Spectroscopy and Crystal Structure Determination of a New Decavanadate

dc.contributorUniversidade de São Paulo (USP)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T14:02:39Z
dc.date.available2014-05-20T14:02:39Z
dc.date.created2014-05-20T14:02:39Z
dc.date.issued2010-11-01
dc.identifierJournal of Chemical Crystallography. New York: Springer/plenum Publishers, v. 40, n. 11, p. 897-901, 2010.
dc.identifier1074-1542
dc.identifierhttp://hdl.handle.net/11449/22087
dc.identifier10.1007/s10870-010-9759-x
dc.identifierWOS:000284078600001
dc.description.abstractSynthesis, infrared spectroscopy and crystal structure of a new potassium decavanadate decahydrate, K-6[V10O28] 10H(2)O, has been reported The infrared spectrum is dominated by decavanadate polyanion and water bands The X-ray crystallography analysis found the compound crystallizes in a triclinic system with the parameters a = 10 5334 (4) angstrom, b = 10 6600 (4) angstrom, c = 17 7351 (5) angstrom, alpha = 76 940 (2)degrees, beta = 75 836 (2)degrees, gamma = 64 776 (2)degrees, V = 1,729 86 (11) A(3), Z = 2, space group P (1) over bar The polyanion consists of ten [VO6] octahedra sharing edges, in which the V-O distances are in good agreement with those reported for other decavanadates The crystal structure is stabilized by potassium cations and water molecules forming a complex pattern of hydrogen bonding and short contact ionic interactions
dc.languageeng
dc.publisherSpringer/plenum Publishers
dc.relationJournal of Chemical Crystallography
dc.relation0.699
dc.relation0,209
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectPotassium decavanadate decahydrate
dc.subjectInfrared spectrum
dc.subjectCrystal structure
dc.subjectMolecular interaction
dc.titleSynthesis, Infrared Spectroscopy and Crystal Structure Determination of a New Decavanadate
dc.typeArtículos de revistas


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