Artículos de revistas
Weathering evolution of the rich-phosphates lateritic mantle in Itacupim Island, Pará, Brazil - mineralogy, micromorphology, and geochemistry
Evolução do Manto de Intemperismo Laterítico Rico em Fosfatos na Ilha de Itacupim (PA) - Mineralogia, Micromorfologia e Geoquímica
Registro en:
10.22456/1807-9806.19520
Autor
DE TOLEDO, MARIA CRISTINA MOTTA
DE OLIVEIRA, SONIA BARROS
DA COSTA, MARCONDES LIMA
PASSOS, CAMILA
DE ALMEIDA, HENRIQUE DINIZ
Resumen
The lateritic mantle overlying ultramafic rocks at Itacupim Island (state of Pará, northern Brazil) comprises 5 horizons. From bottom to top they are: (1) altered rock (hornblende, phlogopite, apatite, magnetite, fissural wavellite, and smaller amounts of smectite or kaolinite), (2) a smectitic saprolite (smectite, wavellite, goethite, and traces of hornblende), a kaolinitic saprolite (kaolinite, wavellite, goethite, and traces of phlogopite), a phosphatic duricrust (crandallite, goethite and hematite), and a ferruginous duricrust (hematite, goethite and crandallite). The mineralogical and chemical composition of the saprolitic and duricrust horizons indicate a discontinuity in the weathering evolution: the P-rich crandallitic duricrusts cannot be derived from the P-poor wavellitic saprolites. Most probably, the duricrusts developed during an earlier stage of the weathering evolution, under a drier climate, when the hypogene phosphates (wavellite and apatite) transformed into crandallite. Under subsequent more humid conditions, the weathering alteration of the parent rock led to the dissolution of the hypogene phosphates, resulting in the P-depleted saprolites. The lateritic mantle overlying ultramafic rocks at Itacupim Island (state of Pará, northern Brazil) comprises 5 horizons. From bottom to top they are: (1) altered rock (hornblende, phlogopite, apatite, magnetite, fissural wavellite, and smaller amounts of smectite or kaolinite), (2) a smectitic saprolite (smectite, wavellite, goethite, and traces of hornblende), a kaolinitic saprolite (kaolinite, wavellite, goethite, and traces of phlogopite), a phosphatic duricrust (crandallite, goethite and hematite), and a ferruginous duricrust (hematite, goethite and crandallite). The mineralogical and chemical composition of the saprolitic and duricrust horizons indicate a discontinuity in the weathering evolution: the P-rich crandallitic duricrusts cannot be derived from the P-poor wavellitic saprolites. Most probably, the duricrusts developed during an earlier stage of the weathering evolution, under a drier climate, when the hypogene phosphates (wavellite and apatite) transformed into crandallite. Under subsequent more humid conditions, the weathering alteration of the parent rock led to the dissolution of the hypogene phosphates, resulting in the P-depleted saprolites.