Artículos de revistas
Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers
Fecha
2010-08-16Registro en:
Pracella, Mariano; Minhaz-Ul Haque, M.; Alvarez, Vera Alejandra; Compatibilization and properties of EVA copolymers containing surface-functionalized cellulose microfibers; Wiley Vch Verlag; Macromolecular Materials And Engineering (print); 295; 10; 16-8-2010; 949-957
1438-7492
Autor
Pracella, Mariano
Minhaz-Ul Haque, M.
Alvarez, Vera Alejandra
Resumen
Cellulose microfibers were modified with two different bi-functional monomers. Composites of EVA copolymer with modified and unmodified cellulose were prepared by melt mixing. The samples were analyzed by SEM, XRD, FT-IR, DSC, TGA, DMTA and tensile mechanical tests. SEM showed that the presence of reactive groups on cellulose surface enhanced the compatibility,improving the fiber/matrix interfacial adhesion.FT-IR disclosed the occurrence of chemical reactions between the functionalized cellulose and polymer chains. The incorporation of fibers affected the crystallization behaviour and crystallinity of the polymer matrix. Composites with GMA modified cellulose displayed better compatibility, higher thermal and mechanical properties.