Pericyclic Cascade toward Isochromenes: Application to the Synthesis of Alkaloid Benzosimuline

dc.creatorRiveira, Martín Jorge
dc.creatorla Venia, Agustina
dc.creatorMischne, Mirta Paulina
dc.date.accessioned2018-07-19T18:50:56Z
dc.date.accessioned2018-11-06T15:36:34Z
dc.date.available2018-07-19T18:50:56Z
dc.date.available2018-11-06T15:36:34Z
dc.date.created2018-07-19T18:50:56Z
dc.date.issued2016-09
dc.identifierRiveira, Martín Jorge; la Venia, Agustina; Mischne, Mirta Paulina; Pericyclic Cascade toward Isochromenes: Application to the Synthesis of Alkaloid Benzosimuline; American Chemical Society; Journal of Organic Chemistry; 81; 17; 9-2016; 7977-7983
dc.identifier0022-3263
dc.identifierhttp://hdl.handle.net/11336/52692
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1899065
dc.description.abstractThe synthesis of biologically active alkaloid benzosimuline, isolated from the shrub Zanthoxylum simulans, is reported. Key transformation involves an oxa-6π electrocyclic ring-opening/hetero-Diels-Alder pericyclic cascade. Although the last aromatization step proved to be cumbersome, this work unfolds a unique route to access interesting molecules from simple precursors.
dc.languageeng
dc.publisherAmerican Chemical Society
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/acs.joc.6b01278
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.joc.6b01278
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectDOMINO REACTIONS
dc.subjectALKALOIDS
dc.subjectHETERO DIELS-ALDER
dc.subjectPERICYCLIC REACTIONS
dc.titlePericyclic Cascade toward Isochromenes: Application to the Synthesis of Alkaloid Benzosimuline
dc.typeArtículos de revistas
dc.typeArtículos de revistas
dc.typeArtículos de revistas


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