Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism

Guastavino, Javier Fernando; Rossi, Roberto Arturo

Artículos de revistas

Fecha

2009-12

Registro en:

Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-2649

0276-7333

http://hdl.handle.net/11336/21698

CONICET Digital

CONICET

http://repositorioslatinoamericanos.uchile.cl/handle/2250/1897241

Autor

Guastavino, Javier Fernando

Rossi, Roberto Arturo

Institución

Consejo Nacional de Investigaciones Científicas y Tecnológicas (Argentina)

Resumen

The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield.

Materias

1,1-DICHLOROCYCLOPROPANES

SRN1 REACTION

1,1-BIS(TRIMETHYLSTANNYL)CYCLOPROPANES

Mostrar el registro completo del ítem