Influence of rhodium content on the behavior of Rh/SiO 2 –Al 2 O 3 catalysts for selective ring opening of decalin

dc.creatorD'ippolito, Silvana Andrea
dc.creatorPirault-Roy, Laurence
dc.creatorEspecel, Catherine
dc.creatorEpron, Florence
dc.creatorPieck, Carlos Luis
dc.date.accessioned2018-05-04T15:38:52Z
dc.date.accessioned2018-11-06T15:17:51Z
dc.date.available2018-05-04T15:38:52Z
dc.date.available2018-11-06T15:17:51Z
dc.date.created2018-05-04T15:38:52Z
dc.date.issued2017-10
dc.identifierD'ippolito, Silvana Andrea; Pirault-Roy, Laurence; Especel, Catherine; Epron, Florence; Pieck, Carlos Luis; Influence of rhodium content on the behavior of Rh/SiO 2 –Al 2 O 3 catalysts for selective ring opening of decalin; Royal Society of Chemistry; RSC Advances; 7; 10-2017; 46803-46811
dc.identifier2046-2069
dc.identifierhttp://hdl.handle.net/11336/44137
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1895746
dc.description.abstractThe influence of the Rh content of catalysts supported on SiO2?Al2O3 (SIRAL 70 and 80, with 70 and 80 wt% of SiO2) on the activity and selectivity for selective ring opening of decalin was studied at 325 and 350 C. An optimum metal content was found at 1.5 wt% of rhodium. Both supports present moderate and strong acid sites. For the selective opening of decalin, the best metal/support combination was found with Rh(1.5)/SIRAL 70 balancing the support acidity together with the hydrogenolytic activity of the metal. A linear correlation was established between the amount of coke deposited and the formation of dehydrogenated compound.
dc.languageeng
dc.publisherRoyal Society of Chemistry
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C7RA08350E
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C7RA08350E
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectSelective ring opening
dc.subjectrhodium
dc.subjectDecalin
dc.titleInfluence of rhodium content on the behavior of Rh/SiO 2 –Al 2 O 3 catalysts for selective ring opening of decalin
dc.typeArtículos de revistas
dc.typeArtículos de revistas
dc.typeArtículos de revistas


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