dc.creator | Barluenga, José | |
dc.creator | González Bobes, Francisco | |
dc.creator | Murguia, Marcelo Cesar | |
dc.creator | Ananthoju, Sreenivasa | |
dc.creator | González, José | |
dc.date.accessioned | 2017-10-19T18:40:31Z | |
dc.date.accessioned | 2018-11-06T15:17:24Z | |
dc.date.available | 2017-10-19T18:40:31Z | |
dc.date.available | 2018-11-06T15:17:24Z | |
dc.date.created | 2017-10-19T18:40:31Z | |
dc.date.issued | 2004-07 | |
dc.identifier | Barluenga, José; González Bobes, Francisco; Murguia, Marcelo Cesar; Ananthoju, Sreenivasa; González, José; Bis(pyridine)iodonium Tetrafluoroborate (IPy2BF4): a versatile oxidizing reagent; Wiley VCH Verlag; Chemistry- A European Journal; 10; 17; 7-2004; 4206-4213 | |
dc.identifier | 0947-6539 | |
dc.identifier | http://hdl.handle.net/11336/26833 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1895683 | |
dc.description.abstract | The use of bis(pyridine)iodonium tetrafluoroborate (IPy2BF4) as an oxidizing agent towards different types of alcohols is reported. The observed reactivity involves different reaction pathways, as a function both of the structures of the starting materials and of the experimental conditions. Interestingly, the title iodine-containing compound is capable of a tuneable reaction with simple cycloalkanols, providing straight and selective access either to ω-iodocarbonyl compounds or to ketones, a previously unreported and chemoselective range of oxidation potential. Furthermore, appropriate conditions for the preparation of aldehydes and esters from primary alcohols by easily performed experimental procedures were also established. The β-scission reactions of cycloalkanols and the α-oxidation processes of primary, secondary and benzylic alcohols are discussed. | |
dc.language | eng | |
dc.publisher | Wiley VCH Verlag | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/chem.200400136 | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/chem.200400136/abstract | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.subject | OXIDATIONS | |
dc.subject | IODATIONS | |
dc.subject | IODONIUM | |
dc.subject | BIS PYRIDINE IODONIUM | |
dc.title | Bis(pyridine)iodonium Tetrafluoroborate (IPy2BF4): a versatile oxidizing reagent | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |