| dc.creator | Postigo, Jose Alberto | |
| dc.date.accessioned | 2017-05-09T18:29:40Z | |
| dc.date.accessioned | 2018-11-06T13:25:25Z | |
| dc.date.available | 2017-05-09T18:29:40Z | |
| dc.date.available | 2018-11-06T13:25:25Z | |
| dc.date.created | 2017-05-09T18:29:40Z | |
| dc.date.issued | 2014-10-15 | |
| dc.identifier | Postigo, Jose Alberto; Photoinduced perfluorobutylation of organic substrates in aqueous media; Comporter; Biointerface Research in Applied Chemistry; 4; 5; 15-10-2014; 865-872 | |
| dc.identifier | 2069-5837 | |
| dc.identifier | http://hdl.handle.net/11336/16147 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1875205 | |
| dc.description.abstract | Hydroperfluorobutylation of a series of electron-deficient and electron-rich alkenes through consecutive radical reactions employing perfluorobutyl iodide, n-C4F9I, and (Me3Si)3SiH as chain carrier/hydrogen atom donor is described. The photoinduced Halogen Atom Transfer (HAT) reactions of both olefins and alkynes with n-C4F9I are also shown to be achieved efficiently in aqueous mixtures. On the other hand, aromatic and heteroaromatic substrates can be perfluorobutylated with high efficiency in a photoinduced fashion by means of a Homolytic Aromatic Substitution (SHA) process which involves an Electron Transfer (ET) and a Proton Transfer (PT) step. | |
| dc.language | eng | |
| dc.publisher | Comporter | |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://biointerfaceresearch.com/?page_id=829 | |
| dc.rights | https://creativecommons.org/licenses/by/2.5/ar/ | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | PERFLUOROBUTYLATION | |
| dc.subject | RADICAL REACTIONS | |
| dc.subject | PHOTOINDUCED | |
| dc.title | Photoinduced perfluorobutylation of organic substrates in aqueous media | |
| dc.type | Artículos de revistas | |
| dc.type | Artículos de revistas | |
| dc.type | Artículos de revistas | |
