dc.creator | Pedro, Juana | |
dc.creator | Andrade, Francisco | |
dc.creator | Magni, Diana | |
dc.creator | Tudino, Mabel Beatriz | |
dc.creator | Bonivardi, Adrian Lionel | |
dc.date.accessioned | 2017-10-19T18:10:49Z | |
dc.date.accessioned | 2018-11-06T11:45:02Z | |
dc.date.available | 2017-10-19T18:10:49Z | |
dc.date.available | 2018-11-06T11:45:02Z | |
dc.date.created | 2017-10-19T18:10:49Z | |
dc.date.issued | 2004-06 | |
dc.identifier | Pedro, Juana; Andrade, Francisco; Magni, Diana; Tudino, Mabel Beatriz; Bonivardi, Adrian Lionel; On-line submicellar enhanced fluorometric determination of Se(IV) with 2,3-diaminonaphthalene; Elsevier Science; Analytica Chimica Acta; 516; 1-2; 6-2004; 229-236 | |
dc.identifier | 0003-2670 | |
dc.identifier | http://hdl.handle.net/11336/26824 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1859080 | |
dc.description.abstract | The flow injection (FI) analytical determination of Se(IV) with 2,3-diaminonaphthalene (DAN) was assayed employing enhanced fluorometric detection. The different variables affecting the reaction rate between Se(IV) and DAN were studied in batch mode, and the best conditions for the 4,5-benzopiazselenol (Se–DAN complex) formation were found. On this basis, two different FI manifolds able to give optimal sensitivity were designed. Once established the optimal flow conditions for the product formation, a submicellar medium of sodium dodecylsulphate with the addition of beta-cyclodextrin was tested to perform enhanced fluorometric detection. A limit of detection of 0.3 ug l-1 of Se(IV), a linear dynamic range ranging between 1 and 500 ug l-1 of Se(IV) and a sampling throughput of 40 samples h-1 were obtained. A full discussion on each stage of the optimisation procedure and the validation of the propose methodology is provided. | |
dc.language | eng | |
dc.publisher | Elsevier Science | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.aca.2004.04.016 | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0003267004004635 | |
dc.rights | https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.title | On-line submicellar enhanced fluorometric determination of Se(IV) with 2,3-diaminonaphthalene | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |