Synthesis of organotin derivatives of optically active eleven-membered macrodiolides

dc.creatorScoccia, Jimena
dc.creatorGerbino, Darío César
dc.creatorPodestá, Julio Cesar
dc.date.accessioned2018-08-01T20:06:42Z
dc.date.accessioned2018-11-06T11:19:32Z
dc.date.available2018-08-01T20:06:42Z
dc.date.available2018-11-06T11:19:32Z
dc.date.created2018-08-01T20:06:42Z
dc.date.issued2016-05-01
dc.identifierScoccia, Jimena; Gerbino, Darío César; Podestá, Julio Cesar; Synthesis of organotin derivatives of optically active eleven-membered macrodiolides; Pergamon-Elsevier Science Ltd; Tetrahedron: Asymmetry; 27; 7-8; 1-5-2016; 352-360
dc.identifier0957-4166
dc.identifierhttp://hdl.handle.net/11336/53818
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1848468
dc.description.abstractThe synthesis and the results obtained in the hydrostannation of eight new TADDOL diacrylates and methacrylates are reported. The addition of triorganotin hydrides, R3SnH, 12-14 (R = nBu, neophyl, Ph, respectively) to diesters 6-11 containing different combinations of substituents at the C-2 carbon of the dioxolane ring, led to macrocyclization products in all cases. The cyclohydrostannation of diacrylate 10 proceeded with complete diastereoselectivity. The cyclohydrostannation of diesters 33 and 34 with hydrides 12 and 14 in all cases only afforded one stannylated macrocycle.
dc.languageeng
dc.publisherPergamon-Elsevier Science Ltd
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0957416616001051
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.tetasy.2016.02.014
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectTADDOLs LIKE UNSATURATED DIESTERS STEREOSELECTIVE CYCLOHYDROSTANNATION
dc.subjectCYCLOHYDROSTANNATION
dc.subjectELEVEN MEMBERED MACROLIDES
dc.titleSynthesis of organotin derivatives of optically active eleven-membered macrodiolides
dc.typeArtículos de revistas
dc.typeArtículos de revistas
dc.typeArtículos de revistas


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