info:eu-repo/semantics/article
Monolithic stirrer reactor: Performance in the partial hydrogenation of sunflower oil
Registro en:
Boldrini, Diego Emmanuel; Sánchez Morales, Jhon Freddy; Tonetto, Gabriela Marta; Damiani, Daniel Eduardo; Monolithic stirrer reactor: Performance in the partial hydrogenation of sunflower oil; American Chemical Society; Industrial & Engineering Chemical Research; 51; 38; 9-2012; 12222-12232
0888-5885
CONICET Digital
CONICET
Autor
Boldrini, Diego Emmanuel
Sánchez Morales, Jhon Freddy
Tonetto, Gabriela Marta
Damiani, Daniel Eduardo
Resumen
In the present paper, the performance of monolithic catalysts obtained from a catalytic converter was analyzed in the partial hydrogenation of sunflower oil. The monoliths were reimpregnated with palladium and installed as a blade in a monolithic stirrer reactor. The use of this type of reactor was explored in the reaction at 373 K and 413 kPa, analyzing the effect variables such as stirrer speed, hydrogen supply, and stirrer design on the catalyst activity and selectivity to trans-isomers and saturated product. The volumetric gas-liquid and liquid-solid mass transfer coefficients were calculated, and the influence of the stirrer speed was examined. Estimations of the Carberry numbers and Weisz-Prater modulus were used for establishing the presence or absence of mass transfer resistances. The performance of the catalyst was studied in consecutive tests, and different procedures for catalyst regeneration were applied. Fil: Boldrini, Diego Emmanuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Sánchez Morales, Jhon Freddy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina