dc.creator | Camargo, Tiago Pacheco | |
dc.creator | Peralta, Rosely A. | |
dc.creator | Moreira, Raphaell | |
dc.creator | Castellano, Eduardo Ernesto | |
dc.creator | Bortoluzzi, Adailton J. | |
dc.creator | Neves, Ademir | |
dc.date.accessioned | 2014-06-28T00:43:35Z | |
dc.date.accessioned | 2018-07-04T16:46:50Z | |
dc.date.available | 2014-06-28T00:43:35Z | |
dc.date.available | 2018-07-04T16:46:50Z | |
dc.date.created | 2014-06-28T00:43:35Z | |
dc.date.issued | 2013-11 | |
dc.identifier | Inorganic Chemistry Communications, Amsterdam : Elsevier BV, v. 37, p. 34-38, Nov. 2013 | |
dc.identifier | 1387-7003 | |
dc.identifier | http://www.producao.usp.br/handle/BDPI/45520 | |
dc.identifier | 10.1016/j.inoche.2013.09.039 | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1640265 | |
dc.description.abstract | The new mononuclear copper(II) complex [CuII(H2LDA)(ClO4)](ClO4) (1) ([H2LDA = N,N′-[bis-(2-hydroxy-3- formyl-5-methylbenzyl)(dimethyl)]-ethylenediamine])with an unusual coordination mode of a salen derivative ligand is reported. The most interesting feature of 1 is that the ligand is doubly protonated and presents significant intermolecular π-stacking interactions, contributing to the dimer structure stabilization in the solid state and in CH3CN and methanolic solutions. The complex was characterized by X-ray crystallography and shows catecholase-like activity in the oxidation of the substrate 3,5-di-tert-butylcatechol (3,5-dtbc), with the formation of H2O2, which kinetic parameters are similar to those observed in conventional dinuclear bridged CuII complexes. | |
dc.language | eng | |
dc.publisher | Elsevier BV | |
dc.publisher | Amsterdam | |
dc.relation | Inorganic Chemistry Communications | |
dc.rights | Copyright Elsevier B.V. | |
dc.rights | restrictedAccess | |
dc.subject | Salen derivative ligand | |
dc.subject | Copper(II) complex | |
dc.subject | π-Stacking | |
dc.subject | Catecholase | |
dc.title | New mononuclear copper(II) complex based on a salen derivative ligand with an unusual coordination and its catecholase activity | |
dc.type | Artículos de revistas | |