dc.creatorCamargo, Tiago Pacheco
dc.creatorPeralta, Rosely A.
dc.creatorMoreira, Raphaell
dc.creatorCastellano, Eduardo Ernesto
dc.creatorBortoluzzi, Adailton J.
dc.creatorNeves, Ademir
dc.date.accessioned2014-06-28T00:43:35Z
dc.date.accessioned2018-07-04T16:46:50Z
dc.date.available2014-06-28T00:43:35Z
dc.date.available2018-07-04T16:46:50Z
dc.date.created2014-06-28T00:43:35Z
dc.date.issued2013-11
dc.identifierInorganic Chemistry Communications, Amsterdam : Elsevier BV, v. 37, p. 34-38, Nov. 2013
dc.identifier1387-7003
dc.identifierhttp://www.producao.usp.br/handle/BDPI/45520
dc.identifier10.1016/j.inoche.2013.09.039
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1640265
dc.description.abstractThe new mononuclear copper(II) complex [CuII(H2LDA)(ClO4)](ClO4) (1) ([H2LDA = N,N′-[bis-(2-hydroxy-3- formyl-5-methylbenzyl)(dimethyl)]-ethylenediamine])with an unusual coordination mode of a salen derivative ligand is reported. The most interesting feature of 1 is that the ligand is doubly protonated and presents significant intermolecular π-stacking interactions, contributing to the dimer structure stabilization in the solid state and in CH3CN and methanolic solutions. The complex was characterized by X-ray crystallography and shows catecholase-like activity in the oxidation of the substrate 3,5-di-tert-butylcatechol (3,5-dtbc), with the formation of H2O2, which kinetic parameters are similar to those observed in conventional dinuclear bridged CuII complexes.
dc.languageeng
dc.publisherElsevier BV
dc.publisherAmsterdam
dc.relationInorganic Chemistry Communications
dc.rightsCopyright Elsevier B.V.
dc.rightsrestrictedAccess
dc.subjectSalen derivative ligand
dc.subjectCopper(II) complex
dc.subjectπ-Stacking
dc.subjectCatecholase
dc.titleNew mononuclear copper(II) complex based on a salen derivative ligand with an unusual coordination and its catecholase activity
dc.typeArtículos de revistas


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