Second-coordination-sphere effects increase the catalytic efficiency of an extended model for FeIIIMII purple acid phosphatases

dc.creatorSouza, Bernardo de
dc.creatorKreft, Gabriel L.
dc.creatorBortolotto, Tiago
dc.creatorTerenzi, Hernán
dc.creatorBortoluzzi, Adailton J.
dc.creatorCastellano, Eduardo Ernesto
dc.creatorPeralta, Rosely A.
dc.creatorDomingos, Josiel B.
dc.creatorNeves, Ademir
dc.date.accessioned2014-06-04T19:07:01Z
dc.date.accessioned2018-07-04T16:46:29Z
dc.date.available2014-06-04T19:07:01Z
dc.date.available2018-07-04T16:46:29Z
dc.date.created2014-06-04T19:07:01Z
dc.date.issued2013-04
dc.identifierInorganic Chemistry, Washington, DC : American Chemical Society - ACS, v. 52, n. 7, p. 3594-3596, Apr. 2013
dc.identifier0020-1669
dc.identifierhttp://www.producao.usp.br/handle/BDPI/45267
dc.identifier10.1021/ic400025j
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1640187
dc.description.abstractHerein we describe the synthesis of a new heterodinuclear FeIIICuII model complex for the active site of purple acid phosphatases and its binding to a polyamine chain, a model for the amino acid residues around the active site. The properties of these systems and their catalytic activity in the hydrolysis of bis(2,4-dinitrophenyl)phosphate are compared, and conclusions regarding the effects of the second coordination sphere are drawn. The positive effect of the polymeric chain on DNA hydrolysis is also described and discussed.
dc.languageeng
dc.publisherAmerican Chemical Society - ACS
dc.publisherWashington, DC
dc.relationInorganic Chemistry
dc.rightsCopyright American Chemical Society
dc.rightsrestrictedAccess
dc.titleSecond-coordination-sphere effects increase the catalytic efficiency of an extended model for FeIIIMII purple acid phosphatases
dc.typeArtículos de revistas


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