dc.creatorMiguel Rustoy, Eduardo
dc.creatorAgotegaray, Mariela
dc.creatorEnrique Piro, Oscar
dc.creatorCastellano, Eduardo Ernesto
dc.date.accessioned2013-11-06T12:49:37Z
dc.date.accessioned2018-07-04T16:24:02Z
dc.date.available2013-11-06T12:49:37Z
dc.date.available2018-07-04T16:24:02Z
dc.date.created2013-11-06T12:49:37Z
dc.date.issued2012
dc.identifierJOURNAL OF COORDINATION CHEMISTRY, ABINGDON, v. 65, n. 13, supl. 4, Part 1-2, pp. 2341-2352, DEC, 2012
dc.identifier0095-8972
dc.identifierhttp://www.producao.usp.br/handle/BDPI/42017
dc.identifier10.1080/00958972.2012.691477
dc.identifierhttp://dx.doi.org/10.1080/00958972.2012.691477
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1635334
dc.description.abstractEight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu-2(Fasp)(4)(MeCN)(2)] center dot 2MeCN (1), [Cu-2(Clasp)(4)(MeCN)(2)]center dot 2MeCN (2), [Cu-2(Brasp)(4) (MeCn)(2)] center dot 2MeCn (3), {[Cu-2(Fasp)(4)(Pyrz)] center dot 2MeCN}(n) (4) {[Cu-2(Clasp)(4)(Pyrz)] center dot 2MeCN}(n) (5), [Cu-2(Brasp)(4)(Pyrz)](n) (6), [Cu-2(Clasp)(4)(4,4'-Bipy)](n) (7), and [Cu-2(Brasp)(4)(4,4'-Bipy)](n) (8) (Fasp: fluor-aspirinate; Clasp: chloro-aspirinate; Brasp: bromo-aspirinate; MeCN: acetonitrile; Pyrz: pyrazine; 4,4'-Bipy: 4,4'-bipyridine). The crystal structure of two 2 and 4 have been determined by X-ray diffraction methods. All compounds have been studied employing elemental analysis, IR, and UV-Visible spectroscopic techniques. The results have been compared with previous data reported for complexes with similar structures.
dc.languageeng
dc.publisherTAYLOR & FRANCIS LTD
dc.publisherABINGDON
dc.relationJOURNAL OF COORDINATION CHEMISTRY
dc.rightsCopyright TAYLOR & FRANCIS LTD
dc.rightsrestrictedAccess
dc.subjectCOPPER(II) COMPLEXES
dc.subjectHALOASPIRINATE ANIONS
dc.subjectCRYSTAL STRUCTURES
dc.titleCrystal structure and spectroscopic properties of polymeric adducts of the tetra-mu-haloaspirinate-dicopper(II)
dc.typeArtículos de revistas


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