dc.creator | Miguel Rustoy, Eduardo | |
dc.creator | Agotegaray, Mariela | |
dc.creator | Enrique Piro, Oscar | |
dc.creator | Castellano, Eduardo Ernesto | |
dc.date.accessioned | 2013-11-06T12:49:37Z | |
dc.date.accessioned | 2018-07-04T16:24:02Z | |
dc.date.available | 2013-11-06T12:49:37Z | |
dc.date.available | 2018-07-04T16:24:02Z | |
dc.date.created | 2013-11-06T12:49:37Z | |
dc.date.issued | 2012 | |
dc.identifier | JOURNAL OF COORDINATION CHEMISTRY, ABINGDON, v. 65, n. 13, supl. 4, Part 1-2, pp. 2341-2352, DEC, 2012 | |
dc.identifier | 0095-8972 | |
dc.identifier | http://www.producao.usp.br/handle/BDPI/42017 | |
dc.identifier | 10.1080/00958972.2012.691477 | |
dc.identifier | http://dx.doi.org/10.1080/00958972.2012.691477 | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1635334 | |
dc.description.abstract | Eight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu-2(Fasp)(4)(MeCN)(2)] center dot 2MeCN (1), [Cu-2(Clasp)(4)(MeCN)(2)]center dot 2MeCN (2), [Cu-2(Brasp)(4) (MeCn)(2)] center dot 2MeCn (3), {[Cu-2(Fasp)(4)(Pyrz)] center dot 2MeCN}(n) (4) {[Cu-2(Clasp)(4)(Pyrz)] center dot 2MeCN}(n) (5), [Cu-2(Brasp)(4)(Pyrz)](n) (6), [Cu-2(Clasp)(4)(4,4'-Bipy)](n) (7), and [Cu-2(Brasp)(4)(4,4'-Bipy)](n) (8) (Fasp: fluor-aspirinate; Clasp: chloro-aspirinate; Brasp: bromo-aspirinate; MeCN: acetonitrile; Pyrz: pyrazine; 4,4'-Bipy: 4,4'-bipyridine). The crystal structure of two 2 and 4 have been determined by X-ray diffraction methods. All compounds have been studied employing elemental analysis, IR, and UV-Visible spectroscopic techniques. The results have been compared with previous data reported for complexes with similar structures. | |
dc.language | eng | |
dc.publisher | TAYLOR & FRANCIS LTD | |
dc.publisher | ABINGDON | |
dc.relation | JOURNAL OF COORDINATION CHEMISTRY | |
dc.rights | Copyright TAYLOR & FRANCIS LTD | |
dc.rights | restrictedAccess | |
dc.subject | COPPER(II) COMPLEXES | |
dc.subject | HALOASPIRINATE ANIONS | |
dc.subject | CRYSTAL STRUCTURES | |
dc.title | Crystal structure and spectroscopic properties of polymeric adducts of the tetra-mu-haloaspirinate-dicopper(II) | |
dc.type | Artículos de revistas | |