STUDY BY MASS SPECTROMETRY OF SOLUTIONS OF [HYDROXY(TOSYLOXY)IODO]BENZENE: PROPOSED DISPROPORTIONATION MECHANISMS

dc.creatorVasconcelos, Ramon S.
dc.creatorSilva Jr., Luiz F.
dc.creatorLopes, Norberto P.
dc.date.accessioned2013-11-07T09:44:09Z
dc.date.accessioned2018-07-04T16:22:00Z
dc.date.available2013-11-07T09:44:09Z
dc.date.available2018-07-04T16:22:00Z
dc.date.created2013-11-07T09:44:09Z
dc.date.issued2012
dc.identifierQUIMICA NOVA, SAO PAULO, v. 35, n. 8, pp. 1593-1599, JAN, 2012
dc.identifier0100-4042
dc.identifierhttp://www.producao.usp.br/handle/BDPI/42758
dc.identifier10.1590/S0100-40422012000800019
dc.identifierhttp://dx.doi.org/10.1590/S0100-40422012000800019
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1634893
dc.description.abstractSTUDY BY MASS SPECTROMETRY OF SOLUTIONS OF [HYDROXY(TOSYLOXY)IODO]BENZENE: PROPOSED DISPROPORTIONATION MECHANISMS. Solutions of [hydroxy(tosyloxy)iodo]benzene (HTIB or Koser's reagent) in acetonitrile were analyzed using high resolution electrospray ionization mass spectrometry (ESI-MS) and electrospray ionization tandem mass spectrometry (ESI-MS/MS) under different conditions. Several species were characterized in these analyses. Based on these data, mechanisms were proposed for the disproportionation of the iodine(III) compounds in iodine(V) and iodine(I) species.
dc.languagepor
dc.publisherSOC BRASILEIRA QUIMICA
dc.publisherSAO PAULO
dc.relationQUIMICA NOVA
dc.rightsCopyright SOC BRASILEIRA QUIMICA
dc.rightsopenAccess
dc.subjectHYPERVALENT IODINE
dc.subjectELECTROSPRAY IONIZATION MASS SPECTROMETRY
dc.subjectDISPROPORTIONATION
dc.titleSTUDY BY MASS SPECTROMETRY OF SOLUTIONS OF [HYDROXY(TOSYLOXY)IODO]BENZENE: PROPOSED DISPROPORTIONATION MECHANISMS
dc.typeArtículos de revistas


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