Metallic chalcogenolates mediated modular Michael-aldol cascade reaction: an easy route to multi-functionalized chalcogenides and Morita-Baylis-Hillman adducts

dc.creatorSousa, Bruno A.
dc.creatorKeppler, Arthur F.
dc.creatorGariani, Rogerio A.
dc.creatorComasseto, Joao V.
dc.creatorDos Santos, Alcindo A.
dc.date.accessioned2013-08-22T17:02:26Z
dc.date.accessioned2018-07-04T15:55:40Z
dc.date.available2013-08-22T17:02:26Z
dc.date.available2018-07-04T15:55:40Z
dc.date.created2013-08-22T17:02:26Z
dc.date.issued2012
dc.identifierTETRAHEDRON, OXFORD, v. 68, n. 51, supl. 1, Part 1, pp. 10406-10413, DEC 23, 2012
dc.identifier0040-4020
dc.identifierhttp://www.producao.usp.br/handle/BDPI/32678
dc.identifier10.1016/j.tet.2012.09.027
dc.identifierhttp://dx.doi.org/10.1016/j.tet.2012.09.027
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1629294
dc.description.abstractChalcogenolate mediated Michael-aldol cascade reactions consists of a very efficient route to multi-functionalized gamma-hydroxichalcogenides. Although, when selenolates are employed, these gamma-hydroxichalcogenides can be readily converted into the corresponding Morita-Baylis-Hillman adducts by oxidative elimination of the selenium moiety. In this context, herein we present a complete study on the scope and limitations of this reaction. (C) 2012 Elsevier Ltd. All rights reserved.
dc.languageeng
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.publisherOXFORD
dc.relationTETRAHEDRON
dc.rightsCopyright PERGAMON-ELSEVIER SCIENCE LTD
dc.rightsclosedAccess
dc.subjectMICHAEL-ALDOL
dc.subjectCASCADE REACTION
dc.subjectCHALCOGENS
dc.subjectORGANOMETALLICS
dc.subjectMORITA-BAYLIS-HILLMAN
dc.titleMetallic chalcogenolates mediated modular Michael-aldol cascade reaction: an easy route to multi-functionalized chalcogenides and Morita-Baylis-Hillman adducts
dc.typeArtículos de revistas


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