| dc.creator | GUILHERME, Luciana Rebelo | |
| dc.creator | MASSABNI, Antonio Carlos | |
| dc.creator | DAMETTO, Alessandra Cristina | |
| dc.creator | CORREA, Rodrigo de Souza | |
| dc.creator | ARAUJO, Alexandre Suman de | |
| dc.date.accessioned | 2012-10-20T04:25:06Z | |
| dc.date.accessioned | 2018-07-04T15:44:44Z | |
| dc.date.available | 2012-10-20T04:25:06Z | |
| dc.date.available | 2018-07-04T15:44:44Z | |
| dc.date.created | 2012-10-20T04:25:06Z | |
| dc.date.issued | 2010 | |
| dc.identifier | JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, v.40, n.11, p.897-901, 2010 | |
| dc.identifier | 1074-1542 | |
| dc.identifier | http://producao.usp.br/handle/BDPI/30158 | |
| dc.identifier | 10.1007/s10870.010.9759.x | |
| dc.identifier | http://dx.doi.org/10.1007/s10870.010.9759.x | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1626798 | |
| dc.description.abstract | Synthesis, infrared spectroscopy and crystal structure of a new potassium decavanadate decahydrate, K(6)[V(10)O(28)] 10H(2)O, has been reported The infrared spectrum is dominated by decavanadate polyanion and water bands The X-ray crystallography analysis found the compound crystallizes in a triclinic system with the parameters a = 10 5334 (4) angstrom, b = 10 6600 (4) angstrom, c = 17 7351 (5) angstrom, alpha = 76 940 (2)degrees, beta = 75 836 (2)degrees, gamma = 64 776 (2)degrees, V = 1,729 86 (11) A(3), Z = 2, space group P (1) over bar The polyanion consists of ten [VO(6)] octahedra sharing edges, in which the V-O distances are in good agreement with those reported for other decavanadates The crystal structure is stabilized by potassium cations and water molecules forming a complex pattern of hydrogen bonding and short contact ionic interactions | |
| dc.language | eng | |
| dc.publisher | SPRINGER/PLENUM PUBLISHERS | |
| dc.relation | Journal of Chemical Crystallography | |
| dc.rights | Copyright SPRINGER/PLENUM PUBLISHERS | |
| dc.rights | restrictedAccess | |
| dc.subject | Potassium decavanadate decahydrate | |
| dc.subject | Infrared spectrum | |
| dc.subject | Crystal structure | |
| dc.subject | Molecular interaction | |
| dc.title | Synthesis, Infrared Spectroscopy and Crystal Structure Determination of a New Decavanadate | |
| dc.type | Artículos de revistas | |
