| dc.creator | BARBOSA, Marilia I. F. | |
| dc.creator | SANTOS, Edjane R. dos | |
| dc.creator | GRAMINHA, Angelica E. | |
| dc.creator | BOGADO, Andre L. | |
| dc.creator | TEIXEIRA, Leticia R. | |
| dc.creator | BERALDO, Heloisa | |
| dc.creator | TREVISAN, Maria Teresa S. | |
| dc.creator | ELLENA, Javier | |
| dc.creator | CASTELLANO, Eduardo Ernesto | |
| dc.creator | RODRIGUES, Bernardo L. | |
| dc.creator | ARAUJO, Marcio P. de | |
| dc.creator | BATISTA, Alzir A. | |
| dc.date.accessioned | 2012-10-20T04:22:19Z | |
| dc.date.accessioned | 2018-07-04T15:44:20Z | |
| dc.date.available | 2012-10-20T04:22:19Z | |
| dc.date.available | 2018-07-04T15:44:20Z | |
| dc.date.created | 2012-10-20T04:22:19Z | |
| dc.date.issued | 2011 | |
| dc.identifier | POLYHEDRON, v.30, n.1, p.41-46, 2011 | |
| dc.identifier | 0277-5387 | |
| dc.identifier | http://producao.usp.br/handle/BDPI/30082 | |
| dc.identifier | 10.1016/j.poly.2010.09.025 | |
| dc.identifier | http://dx.doi.org/10.1016/j.poly.2010.09.025 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1626722 | |
| dc.description.abstract | The complex mer-[RuCl(3)(dppb)(H(2)O)] [dppb = 1,4-bis(diphenylphosphino)butane] was used as a precursor in the synthesis of the complexes tc-[RuCl(2)(CO)(2)(dppb)], ct-[RuCl(2)(CO)(2)(dppb)]. cis-[RuCl(2)(dppb)(Cl-bipy)], [RuCl(2Ac4mT)(dppb)] (2Ac4mT = N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone ion) and trans-[RuCl(2)(dppb)(mang)] (mang = mangiferin or 1,3,6,7-tetrahydroxyxanthone-C2-beta-D-glucoside) complexes. For the synthesis of Run complexes, the Ru(III) atom in mer-[RuCl(3)(dppb)(H(2)O)] may be reduced by H(2)(g), forming the intermediate [Ru(2)Cl(4)(dppb)(2)], or by a ligand (such as H2Ac4mT or mangiferin). The X-ray structures of the cis-[RuCl(2)(dppb)(Cl-bipy)], tc-[RuCl(2)(CO)(2)(dppb)] and [RuCl(2Ac4mT)(dPpb)] complexes were determined. (C) 2010 Elsevier Ltd. All rights reserved. | |
| dc.language | eng | |
| dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | |
| dc.relation | Polyhedron | |
| dc.rights | Copyright PERGAMON-ELSEVIER SCIENCE LTD | |
| dc.rights | restrictedAccess | |
| dc.subject | Ruthenium complexes | |
| dc.subject | Mangiferin | |
| dc.subject | N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone | |
| dc.subject | X-ray structures | |
| dc.title | The mer-[RuCl(3)(dppb)(H(2)O)] complex: A versatile tool for synthesis of Ru(II) compounds | |
| dc.type | Artículos de revistas | |
