Stereochemistry of cyclopentane derivatives from (2,3)J(CH) dependence on dihedral angle (theta H-C-C-X)

dc.creatorLACERDA JR., Valdemar
dc.creatorSILVA, Gil V. J. da
dc.creatorCONSTANTINO, Mauricio G.
dc.creatorSANTOS, Reginaldo B. dos
dc.creatorCASTRO, Eustaquio V. R. de
dc.creatorSILVA, Renzo C.
dc.date.accessioned2012-10-19T14:14:36Z
dc.date.accessioned2018-07-04T15:01:31Z
dc.date.available2012-10-19T14:14:36Z
dc.date.available2018-07-04T15:01:31Z
dc.date.created2012-10-19T14:14:36Z
dc.date.issued2008
dc.identifierMAGNETIC RESONANCE IN CHEMISTRY, v.46, n.3, p.268-273, 2008
dc.identifier0749-1581
dc.identifierhttp://producao.usp.br/handle/BDPI/20772
dc.identifier10.1002/mrc.2182
dc.identifierhttp://dx.doi.org/10.1002/mrc.2182
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1617551
dc.description.abstractThe (2,3)J(CH) dependence on dihedral angle (theta H-C-C-X) for cyclopentane derivatives was investigated. We observed that the combined use of experimentally obtained (2,3)J(CH) values and the theoretically determined dihedral angles between the corresponding nuclei can be used to infer the relative stereochemistry of the ring substituents in cyclopentane derivatives. There is a good correlation between the magnitude of (3)J(CH) and the dihedral angle between the hydrogen and the coupled carbon (R-2 = 0.88). Copyright (C) 2008 John Wiley & Sons, Ltd.
dc.languageeng
dc.publisherJOHN WILEY & SONS LTD
dc.relationMagnetic Resonance in Chemistry
dc.rightsCopyright JOHN WILEY & SONS LTD
dc.rightsrestrictedAccess
dc.subjectstereochemistry
dc.subject(2,3)J(CH) dihedral angle dependence
dc.subjectcyclopentane derivatives
dc.subjectheteronuclear long-range spin-spin coupling constants
dc.subjectNMR spectroscopy
dc.subjectG-BIRDR,X-CPMG-HSQMBC pulse sequence
dc.titleStereochemistry of cyclopentane derivatives from (2,3)J(CH) dependence on dihedral angle (theta H-C-C-X)
dc.typeArtículos de revistas


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