Synthesis of (-)-hinokinin by oxidation of (-)-cubebin catalyzed by biomimetic metalloporphyrin catalytic systems

dc.creatorANDRADE, Leonardo N.
dc.creatorBIZAIA, Natalia
dc.creatorCAETANO, Bruno L.
dc.creatorSILVA, MArcio L. A.
dc.creatorCUNHA, Wilson R.
dc.creatorSILVA FILHO, Adernar A. da
dc.creatorCALEFI, Paulo S.
dc.creatorNASSAR, Eduardo J.
dc.creatorBASTOS, Jairo K.
dc.creatorCIUFFI, Katia J.
dc.date.accessioned2012-10-19T03:42:25Z
dc.date.accessioned2018-07-04T14:58:20Z
dc.date.available2012-10-19T03:42:25Z
dc.date.available2018-07-04T14:58:20Z
dc.date.created2012-10-19T03:42:25Z
dc.date.issued2009
dc.identifierCATALYSIS COMMUNICATIONS, v.10, n.5, p.669-672, 2009
dc.identifier1566-7367
dc.identifierhttp://producao.usp.br/handle/BDPI/20203
dc.identifier10.1016/j.catcom.2008.11.013
dc.identifierhttp://dx.doi.org/10.1016/j.catcom.2008.11.013
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1616987
dc.description.abstractA catalytic system consisting of iron tetraphenylporphyrin supported on an alumina matrix for oxidation of (-)-cubebin with iodosylbenzene or hydrogen peroxide is reported. Conversion of (-)-cubebin is very efficient (100%) with 100% selectivity producing only (-)-hinokinin when iodosylbenzene is used as the oxidant and 70% conversion with 100% selectivity when hydrogen peroxide is the oxidant at room temperature under atmospheric pressure. (c) 2008 Elsevier B.V. All rights reserved.
dc.languageeng
dc.publisherELSEVIER SCIENCE BV
dc.relationCatalysis Communications
dc.rightsCopyright ELSEVIER SCIENCE BV
dc.rightsclosedAccess
dc.subjectBiomimetic catalysis
dc.subjectFe-porphyrin
dc.subject(-)-Hinokinin
dc.subject(-)-Cubebin
dc.subjectOxidation
dc.titleSynthesis of (-)-hinokinin by oxidation of (-)-cubebin catalyzed by biomimetic metalloporphyrin catalytic systems
dc.typeArtículos de revistas


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