Photochemical cleavage of nitrate ion coordinated to a Cr(III) porphyrin#

dc.creatorRADFORD, Robert J.
dc.creatorLIM, Mark D.
dc.creatorSILVA, Roberto Santana Da
dc.creatorFORD, Peter C.
dc.date.accessioned2012-10-19T03:40:27Z
dc.date.accessioned2018-07-04T14:57:30Z
dc.date.available2012-10-19T03:40:27Z
dc.date.available2018-07-04T14:57:30Z
dc.date.created2012-10-19T03:40:27Z
dc.date.issued2010
dc.identifierJOURNAL OF COORDINATION CHEMISTRY, v.63, n.14-16, p.2743-2749, 2010
dc.identifier0095-8972
dc.identifierhttp://producao.usp.br/handle/BDPI/20015
dc.identifier10.1080/00958972.2010.492217
dc.identifierhttp://dx.doi.org/10.1080/00958972.2010.492217
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1616799
dc.description.abstractPhotolysis of the nitrato chromium(III) tetraphenylporphyrinato compound Cr(TPP)(NO(3)) (TPP, tetraphenylporphyrin) in toluene solution clearly leads to the formation of the Cr(IV) oxo complex Cr(TPP)(O) with a quantum yield of 0.011. The other product, NO(2), was detected quantitatively by its reaction with the spin trapping agent 2,2,6,6-tetramethyl-piperidine-1-oxyl.
dc.languageeng
dc.publisherTAYLOR & FRANCIS LTD
dc.relationJournal of Coordination Chemistry
dc.rightsCopyright TAYLOR & FRANCIS LTD
dc.rightsrestrictedAccess
dc.subjectChromium(III)
dc.subjectPhotochemistry
dc.subjectNitrite
dc.subjectNitrogen dioxide
dc.titlePhotochemical cleavage of nitrate ion coordinated to a Cr(III) porphyrin#
dc.typeArtículos de revistas


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