Expanding cyclitol structural diversity by biocatalysis and metalocatalysis. A click chemistry approach

dc.creatorSOVERA, Victoria de la
dc.creatorBELLOMO, Ana
dc.creatorPENA, Jesus M.
dc.creatorGONZALEZ, David
dc.creatorSTEFANI, Helio A.
dc.date.accessioned2012-10-19T03:17:19Z
dc.date.accessioned2018-07-04T14:55:55Z
dc.date.available2012-10-19T03:17:19Z
dc.date.available2018-07-04T14:55:55Z
dc.date.created2012-10-19T03:17:19Z
dc.date.issued2011
dc.identifierMOLECULAR DIVERSITY, v.15, n.1, Special Issue, p.163-172, 2011
dc.identifier1381-1991
dc.identifierhttp://producao.usp.br/handle/BDPI/19655
dc.identifier10.1007/s11030-010-9237-6
dc.identifierhttp://dx.doi.org/10.1007/s11030-010-9237-6
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1616442
dc.description.abstractThe palladium catalyzed cross-coupling reaction of phenyltrifluoroborate with a chemoenzymatically derived bromoazidoconduritol, combined with 1,3-dipolar cycloaddition, with a variety of alkynes is described. Fourteen new compounds were synthesized in moderate to good yields. The click chemistry reaction can be effected by using sodium ascorbate and CuSO(4) center dot 5H(2)O as catalyst in toluene-H(2)O at room temperature.
dc.languageeng
dc.publisherSPRINGER
dc.relationMolecular Diversity
dc.rightsCopyright SPRINGER
dc.rightsclosedAccess
dc.subjectOrganotrifloroborates
dc.subjectSuzuki-Miyaura
dc.subjectClick chemistry
dc.subjectChemoenzymatic synthesis
dc.titleExpanding cyclitol structural diversity by biocatalysis and metalocatalysis. A click chemistry approach
dc.typeArtículos de revistas


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