Artículos de revistas
Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea
Fecha
2009Registro en:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, v.65, p.O648-U2960, 2009
1600-5368
10.1107/S1600536808044085
Autor
ESTEVEZ-HERNANDEZ, O.
CORREA, Rodrigo S.
ELLENA, Javier
DUQUE, J.
Institución
Resumen
The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothiocyanate and N-benzylaniline in dry acetone and the structure redetermined. The structure [Otazo-Sanchez et al. (2001). J. Chem. Soc. Perkin Trans. 2, pp. 2211-2218] has been re-determined in order to establish the intramolecular and intermolecular interactions. The thiourea group is in the thioamide form. The thiourea group makes a dihedral angle of 29.2 (6)degrees with the furoyl group. In the crystal structure, molecules are linked by intermolecular C-H center dot center dot center dot O interactions, forming one-dimensional chains along the a axis. An intramolecular N-H center dot center dot center dot O hydrogen bond is also present.