Direct Detection Of Triacetone Triperoxide (tatp) In Real Banknotes From Atm Explosion By Easi-ms

dc.creatorCorrea
dc.creatorDeleon Nascimento; Melendez-Perez
dc.creatorJose J.; Zacca
dc.creatorJorge Jardim; Borges
dc.creatorRodrigo; Schmidt
dc.creatorEduardo Morgado; Eberlin
dc.creatorMarcos Nogueira; Meurer
dc.creatorEduardo Cesar
dc.date2017
dc.dateabr
dc.date2017-11-13T13:57:37Z
dc.date2017-11-13T13:57:37Z
dc.date.accessioned2018-03-29T06:10:56Z
dc.date.available2018-03-29T06:10:56Z
dc.identifierPropellants Explosives Pyrotechnics. Wiley-v C H Verlag Gmbh, v. 42, p. 370 - 375, 2017.
dc.identifier0721-3115
dc.identifier1521-4087
dc.identifierWOS:000399733700003
dc.identifier10.1002/prep.201600046
dc.identifierhttp://onlinelibrary.wiley.com/doi/10.1002/prep.201600046/abstract
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/330056
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1367081
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.descriptionIn Brazil, automated teller machine (ATM) has become a major target of theft incursions toward explosion. Efficient analysis of explosives residues on suspect banknotes is a serious issue in forensic labs, and guide to the crime solution. Easy ambient sonic-spray ionization mass spectrometry (EASI-MS) is shown to be a simple and selective screening tool to identify peroxide explosives on real banknotes collected from ATM explosion. Analyses were carried out directly on the banknotes surfaces without any sample preparation, identifying triacetone triperoxide (TATP) and diacetone diperoxide (DADP). Homemade EASI source was coupled to ultrahigh-resolution and ultrahigh accuracy FT-ICR MS and revealed the ion of m/z 245 correspondent to sodiated TATP [C9H18O6Na](+) and the ion of m/z 171 related to sodiated DADP [C6H12O4Na](+), ions that is the sodiated DADP and the ions of m/z 173 and 189 related to [C6H14O4Na](+) and [C6H14O4K](+), respectively, which are associated to chemical markers of TATP domestic route synthesis. EASI source coupled to a single quadrupole mass spectrometer provides an intelligent and simple way to identify the explosives TATP, DADP and its domestic synthesis markers.
dc.description42
dc.description4
dc.description370
dc.description375
dc.descriptionCAPES - Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior [23038.006844/2014-46]
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.languageEnglish
dc.publisherWiley-V C H Verlag Gmbh
dc.publisherWeinhem
dc.relationPropellants Explosives Pyrotechnics
dc.rightsfechado
dc.sourceWOS
dc.subjectForensic Science
dc.subjectExplosive Detection
dc.subjectAmbient Mass Spectrometry
dc.subjectEasy Ambient Sonic-spray Ionization Mass Spectrometry (easi-ms)
dc.subjectTriacetone Triperoxide (tatp)
dc.titleDirect Detection Of Triacetone Triperoxide (tatp) In Real Banknotes From Atm Explosion By Easi-ms
dc.typeArtículos de revistas


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