dc.creatorOliveira
dc.creatorAndrea; Gonzalez
dc.creatorMario Henrique; Queiroz
dc.creatorHelena Muller; Cadore
dc.creatorSolange
dc.date2016
dc.datedez
dc.date2017-11-13T13:56:38Z
dc.date2017-11-13T13:56:38Z
dc.date.accessioned2018-03-29T06:09:58Z
dc.date.available2018-03-29T06:09:58Z
dc.identifierFood Chemistry. Elsevier Sci Ltd, v. 213, p. 76 - 82, 2016.
dc.identifier0308-8146
dc.identifier1873-7072
dc.identifierWOS:000380289900010
dc.identifier10.1016/j.foodchem.2016.06.055
dc.identifierhttp://www.sciencedirect.com/science/article/pii/S0308814616309487?via%3Dihub
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/329904
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1366929
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionThe inorganic fraction of arsenic species, iAs = Sigma[As(III) + As(V)] present in fish samples can be quantified in the presence of other arsenic species also found in fishes, such as: monomethylarsonic acid (MMA), dimethylarsinic acid (DMA) and arsenobetaine (AsB). The toxic arsenic fraction was selected taking into account the dissociation constants of these arsenic species in different hydrogen ions concentration leading to the arsine formation from iAs compounds detected as As(III) by HG AAS. For thus, a microwave assisted extraction was carried out using HCl 1 mol L-1 in order to maintain the integrity of the arsenic species in this mild extraction media. Recovery experiments were done for iAs fraction, in the presence of other arsenic species. The recovery values obtained for iAs fraction added were quantitative about 87-107% (for N = 3, RSD <= 3%). The limit of detection (LOD), and the limit of quantification (LOQ), were 5 mu g kg(-1) and 16 mu g kg(-1) respectively. (C) 2016 Elsevier Ltd. All rights reserved.
dc.description213
dc.description76
dc.description82
dc.descriptionNational Counsel of Technological and Scientific Development (CNPq)
dc.descriptionMinistry of Agriculture, Livestock and Food Supply (MAPA)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.languageEnglish
dc.publisherElsevier Sci LTD
dc.publisherOxford
dc.relationFood Chemistry
dc.rightsfechado
dc.sourceWOS
dc.subjectInorganic Arsenic
dc.subjectNon-chromatographic Separation
dc.subjectFish Samples
dc.subjectHydride Generation
dc.titleFractionation Of Inorganic Arsenic By Adjusting Hydrogen Ion Concentration
dc.typeArtículos de revistas


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