dc.creatorCarneiro
dc.creatorJussara F.; Rocha
dc.creatorRobson S.; Hammer
dc.creatorPeter; Bertazzoli
dc.creatorR.; Lanza
dc.creatorM. R. V.
dc.date2016
dc.datemaio
dc.date2017-11-13T13:14:06Z
dc.date2017-11-13T13:14:06Z
dc.date.accessioned2018-03-29T05:51:55Z
dc.date.available2018-03-29T05:51:55Z
dc.identifierApplied Catalysis A-general. Elsevier Science Bv, v. 517, p. 161 - 167, 2016.
dc.identifier0926-860X
dc.identifier1873-3875
dc.identifierWOS:000375162100018
dc.identifier10.1016/j.apcata.2016.03.013
dc.identifierhttp://www-sciencedirect-com.ez88.periodicos.capes.gov.br/science/article/pii/S0926860X16301235?via%3Dihub
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/327111
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1364136
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.descriptionHighly efficient H2O2 electrogeneration is required in the Advanced Oxidation Process for organic wastewater treatment. However, the development of more efficient catalytic particles used in gas diffusion electrodes (GDEs) to enable the oxygen reduction reaction through two-electron transfer is still of great importance. The performance of the Ta2O5 nanoparticles on carbon black in catalyzing the ORR was evaluated using rotating ring-disk electrode. The current efficiency for H2O2 electrogeneration on Ta2O5/C catalyst is 83.2% whereas carbon black exhibits 65.3%. GDEs were constructed using carbon black either unmodified or modified with Ta2O5 nanoparticles. The modified GDE produces 27.9 mg L-1 of H2O2, while the unmodified GDE generates 19.1 mg L-1 of H2O2. Furthermore, the energy consumption for the H2O2 electrogeneration is lower in modified than in unmodified GDE (15.0 kWh vs. 18.8 kWh). The high performance of the GDE (Ta2O5/C) renders it a viable alternative cathode in the electrochemical treatment of wastewaters. (C) 2016 Elsevier B.V. All rights reserved.
dc.description517
dc.description161
dc.description167
dc.descriptionConselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [163689/2015-6, 160507/2011-1, 143345/2011-7, 470079/2013-4]
dc.descriptionFundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2011/14314-1]
dc.descriptionCoordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.languageEnglish
dc.publisherElsevier Science BV
dc.publisherAmsterdam
dc.relationApplied Catalysis A-General
dc.rightsfechado
dc.sourceWOS
dc.subjectTantalum Oxide
dc.subjectOxygen Reduction Reaction
dc.subjectHydrogen Peroxide Electrogeneration
dc.subjectGas Diffusion Electrode
dc.titleHydrogen Peroxide Electrogeneration In Gas Diffusion Electrode Nanostructured With Ta2o5
dc.typeArtículos de revistas


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