dc.creatorBittencourt
dc.creatorSamara Storion; Hoga
dc.creatorHeloisa Emi; Torres
dc.creatorRicardo Belchior; Hallak d'Angelo
dc.creatorJose Vicente
dc.date2017
dc.datefev
dc.date2017-11-13T11:32:25Z
dc.date2017-11-13T11:32:25Z
dc.date.accessioned2018-03-29T05:47:05Z
dc.date.available2018-03-29T05:47:05Z
dc.identifierJournal Of Chemical Thermodynamics. Academic Press Ltd- Elsevier Science Ltd, v. 105, p. 238 - 252, 2017.
dc.identifier0021-9614
dc.identifier1096-3626
dc.identifierWOS:000390495700029
dc.identifier10.1016/j.jct.2016.09.007
dc.identifierhttp://www-sciencedirect-com.ez88.periodicos.capes.gov.br/science/article/pii/S0021961416302579
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/326076
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1363082
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.descriptionIn this work, density and speed of sound of binary mixtures of (n-butylammonium butanoate ionic liquid (N4Bu) + alcohols (methanol, ethanol, 1-propanol, 1-butanol and 1-pentanol)) have been measured as a function of composition at T = (293.15-313.15) K and atmospheric pressure. The results were used to calculate the excess molar volume, V-m(E), and deviation in isentropic compressibility, Delta Kappa(s), and correlated to the Redlich-Kister polynomial equation. N4Bu was synthesized by the method of acid-base neutralization reaction using n-butylamine and butanoic acid, and characterized using H-1 NMR, C-13 NMR and FTIR spectroscopy techniques. For all systems studied, the values of excess molar volumes and deviations in isentropic compressibility were negative over the entire composition range. The results obtained were discussed in terms of structural effects and intermolecular interactions between like and unlike molecules. (C) 2016 Elsevier Ltd.
dc.description105
dc.description238
dc.description252
dc.descriptionFundacao Educacional Inaciana Padre Saboia de Medeiros (FEI)
dc.descriptionUniversidade Estadual de Campinas (UNICAMP)
dc.descriptionFundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2009/14556-5]
dc.descriptionCoordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.languageEnglish
dc.publisherAcademic Press Ltd- Elsevier Science Ltd
dc.publisherLondon
dc.relationJournal of Chemical Thermodynamics
dc.rightsfechado
dc.sourceWOS
dc.subjectExcess Molar Volume
dc.subjectDeviation In Isentropic Compressibility
dc.subjectH-1 Nmr, C-13 Nmr And Ftir Spectroscopy
dc.subjectIonic Liquid
dc.subjectAlcohols
dc.titleThermodynamic And Spectroscopic Properties Of Binary Mixtures Of N-butylammonium Butanoate Ionic Liquid With Alcohols At T = (293.15-313.15) K
dc.typeArtículos de revistas


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