dc.creator | Bittencourt | |
dc.creator | Samara Storion; Hoga | |
dc.creator | Heloisa Emi; Torres | |
dc.creator | Ricardo Belchior; Hallak d'Angelo | |
dc.creator | Jose Vicente | |
dc.date | 2017 | |
dc.date | fev | |
dc.date | 2017-11-13T11:32:25Z | |
dc.date | 2017-11-13T11:32:25Z | |
dc.date.accessioned | 2018-03-29T05:47:05Z | |
dc.date.available | 2018-03-29T05:47:05Z | |
dc.identifier | Journal Of Chemical Thermodynamics. Academic Press Ltd- Elsevier Science Ltd, v. 105, p. 238 - 252, 2017. | |
dc.identifier | 0021-9614 | |
dc.identifier | 1096-3626 | |
dc.identifier | WOS:000390495700029 | |
dc.identifier | 10.1016/j.jct.2016.09.007 | |
dc.identifier | http://www-sciencedirect-com.ez88.periodicos.capes.gov.br/science/article/pii/S0021961416302579 | |
dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/326076 | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1363082 | |
dc.description | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | |
dc.description | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) | |
dc.description | In this work, density and speed of sound of binary mixtures of (n-butylammonium butanoate ionic liquid (N4Bu) + alcohols (methanol, ethanol, 1-propanol, 1-butanol and 1-pentanol)) have been measured as a function of composition at T = (293.15-313.15) K and atmospheric pressure. The results were used to calculate the excess molar volume, V-m(E), and deviation in isentropic compressibility, Delta Kappa(s), and correlated to the Redlich-Kister polynomial equation. N4Bu was synthesized by the method of acid-base neutralization reaction using n-butylamine and butanoic acid, and characterized using H-1 NMR, C-13 NMR and FTIR spectroscopy techniques. For all systems studied, the values of excess molar volumes and deviations in isentropic compressibility were negative over the entire composition range. The results obtained were discussed in terms of structural effects and intermolecular interactions between like and unlike molecules. (C) 2016 Elsevier Ltd. | |
dc.description | 105 | |
dc.description | 238 | |
dc.description | 252 | |
dc.description | Fundacao Educacional Inaciana Padre Saboia de Medeiros (FEI) | |
dc.description | Universidade Estadual de Campinas (UNICAMP) | |
dc.description | Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2009/14556-5] | |
dc.description | Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) | |
dc.description | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | |
dc.description | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) | |
dc.language | English | |
dc.publisher | Academic Press Ltd- Elsevier Science Ltd | |
dc.publisher | London | |
dc.relation | Journal of Chemical Thermodynamics | |
dc.rights | fechado | |
dc.source | WOS | |
dc.subject | Excess Molar Volume | |
dc.subject | Deviation In Isentropic Compressibility | |
dc.subject | H-1 Nmr, C-13 Nmr And Ftir Spectroscopy | |
dc.subject | Ionic Liquid | |
dc.subject | Alcohols | |
dc.title | Thermodynamic And Spectroscopic Properties Of Binary Mixtures Of N-butylammonium Butanoate Ionic Liquid With Alcohols At T = (293.15-313.15) K | |
dc.type | Artículos de revistas | |