dc.creatorBastos
dc.creatorFlavio A.; Tubino
dc.creatorMatthieu
dc.date2017
dc.date2017-08-30T17:36:31Z
dc.date2017-08-30T17:36:31Z
dc.date.accessioned2018-03-29T05:29:03Z
dc.date.available2018-03-29T05:29:03Z
dc.identifierJournal Of The Brazilian Chemical Society. Sociedade Brasileira De Química, v. 28, n. 5, p. 747 - 755
dc.identifier0103-5053
dc.identifierS0103-50532017000500747
dc.identifierhttp://www.scielo.br/scielo.php?pid=S0103-50532017000500747&script=sci_arttext
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/324495
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1358713
dc.descriptionThe influence of cashew nutshell liquid (CNSL) in the oxidative stability of biodiesels prepared from oils of soy, corn, canola and sunflower was studied using the Rancimat method. The induction periods at 110 ºC, without and with the addition of CNSL at concentrations of 0.1, 0.5 and 1.0% m/m, were determined and clearly show an important increase in the oxidative stability proportional to the concentration of the additive. For example, with the addition of 0.1% m/m CNSL, the induction period, in hours, increased from 5.7 to 8.5 (soy biodiesel), from 1.7 to 4.0 (sunflower), from 4.3 to 9.3 (corn) and from 6.9 to 12.8 (canola). The rate constants of the oxidation reactions in presence of CNSL were also determined and their respective values are (in h-1): 0.77 ± 0.08, 2.48 ± 0.46, 0.94 ± 0.08, 0.51 ± 0.11. The activation parameters (enthalpy, ∆H*, entropy, ∆S*, and free energy of activation, ∆G*) for the oxidation reactions were determined.
dc.description28
dc.description5
dc.description747
dc.description755
dc.languageIngles
dc.publisherSociedade Brasileira de Química
dc.relationJournal of the Brazilian Chemical Society
dc.rightsaberto
dc.sourceScielo
dc.subjectBiodiesel
dc.subjectOxidative Stability
dc.subjectRancimat
dc.subjectCashew Nutshell Liquid
dc.subjectCnsl
dc.titleThe Use Of The Liquid From Cashew Nut Shells As An Antioxidant In Biodiesel
dc.typeArtículos de revistas


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