Total Synthesis And Tentative Structural Elucidation Of Cryptomoscatone E3: Interplay Of Experimental And Computational Studies

dc.creatorNovaes
dc.creatorLuiz F. T.; Sarotti
dc.creatorAriel M.; Pilli
dc.creatorRonaldo A.
dc.date2015-DEC
dc.date2016-06-07T13:36:06Z
dc.date2016-06-07T13:36:06Z
dc.date.accessioned2018-03-29T01:51:30Z
dc.date.available2018-03-29T01:51:30Z
dc.identifier
dc.identifierTotal Synthesis And Tentative Structural Elucidation Of Cryptomoscatone E3: Interplay Of Experimental And Computational Studies. Amer Chemical Soc, v. 80, p. 12027-12037 DEC-2015.
dc.identifier0022-3263
dc.identifierWOS:000366877900015
dc.identifier10.1021/acs.joc.5b01956
dc.identifierhttp://pubs.acs.org/doi/full/10.1021/acs.joc.5b01956
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/244246
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1307944
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionA successful combination of computational chemistry and total synthesis was explored to tentatively elucidate the absolute configuration of cryptomoscatone E3, a polyketide isolated from the Brazilian tree Cryptocarya mandiocanna. Two independent synthetic approaches are discussed based on asymmetric allylation, ring closing metathesis, and aldol reactions.
dc.description80
dc.description24
dc.description
dc.description12027
dc.description12037
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFAPESP [09/51602-5, 13/07607-8]
dc.descriptionCNPq [131015/2014-1]
dc.description
dc.description
dc.description
dc.languageen
dc.publisherAMER CHEMICAL SOC
dc.publisher
dc.publisherWASHINGTON
dc.relationJOURNAL OF ORGANIC CHEMISTRY
dc.rightsfechado
dc.sourceWOS
dc.subjectCatalyzed Allylic Oxidation
dc.subjectC-13 Chemical-shifts
dc.subjectStereochemical Assignment
dc.subjectChemoenzymatic Synthesis
dc.subjectBryonopsis-laciniosa
dc.subjectNatural-products
dc.subjectNmr
dc.subjectGoniothalamin
dc.subjectEnantiomers
dc.subjectPotent
dc.titleTotal Synthesis And Tentative Structural Elucidation Of Cryptomoscatone E3: Interplay Of Experimental And Computational Studies
dc.typeArtículos de revistas


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