Vapour Liquid Equilibria Of Monocaprylin Plus Palmitic Acid Or Methyl Stearate At P = (1.20 And 2.50) Kpa By Using Dsc Technique

dc.creatorCunico
dc.creatorLarissa P.; Damaceno
dc.creatorDaniela S.; Matricarde Falleiro
dc.creatorRafael M.; Sarup
dc.creatorBent; Abildskov
dc.creatorJens; Ceriani
dc.creatorRoberta; Gani
dc.creatorRafiqul
dc.date2015-DEC
dc.date2016-06-07T13:35:10Z
dc.date2016-06-07T13:35:10Z
dc.date.accessioned2018-03-29T01:50:43Z
dc.date.available2018-03-29T01:50:43Z
dc.identifier
dc.identifierVapour Liquid Equilibria Of Monocaprylin Plus Palmitic Acid Or Methyl Stearate At P = (1.20 And 2.50) Kpa By Using Dsc Technique. Academic Press Ltd- Elsevier Science Ltd, v. 91, p. 108-115 DEC-2015.
dc.identifier0021-9614
dc.identifierWOS:000361472600013
dc.identifier10.1016/j.jct.2015.07.033
dc.identifierhttp://www.sciencedirect.com/science/article/pii/S0021961415002578
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/244066
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1307764
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionThe Differential Scanning Calorimetry (DSC) technique is used for measuring isobaric (vapour + liquid) equilibria for two binary mixtures: {monocaprylin + palmitic acid (system 1) or methyl stearate (system 2)} at two different pressures P = (1.20 and 2.50) kPa. The obtained PTx data are correlated by Wilson, NRTL and UNIQUAC models. The original UNIFAC group contribution method is also considered and new binary interaction parameters for the main groups CH2, CCOO, OH and COOH are regressed, to account for the non-idealities found in these lipid systems. Established thermodynamic consistency tests are applied and attest the quality of the measured data. In terms of relevance of the selected components, system 1 can be found in the purification and deodorization steps during the production of edible oils, while, system 2 can be found in the purification steps of biodiesel. It should be noted that no such data could be found in the open literature, not only for the specific components selected but also for the combination of the classes of components considered; that is, acylglycerol plus fatty acid or fatty ester. (C) 2015 Published by Elsevier Ltd.
dc.description91
dc.description
dc.description
dc.description108
dc.description115
dc.descriptionAlfa Laval Copenhagen S/A
dc.descriptionTechnical University of Denmark
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFAPESP [2013/12735-5]
dc.description
dc.description
dc.description
dc.languageen
dc.publisherACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
dc.publisher
dc.publisherLONDON
dc.relationJOURNAL OF CHEMICAL THERMODYNAMICS
dc.rightsembargo
dc.sourceWOS
dc.subjectDifferential Scanning Calorimetry
dc.subjectEquation-of-state
dc.subjectBinary-mixtures
dc.subjectBoiling Points
dc.subjectLow-pressures
dc.subjectThermophysical Properties
dc.subjectPhase-equilibria
dc.subjectFatty-acids
dc.subjectFree-energy
dc.subjectSystems
dc.titleVapour Liquid Equilibria Of Monocaprylin Plus Palmitic Acid Or Methyl Stearate At P = (1.20 And 2.50) Kpa By Using Dsc Technique
dc.typeArtículos de revistas


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