Sequential Morita-baylis-hillman/achmatowicz Reactions: An Expeditious Access To Pyran-3(6h)-ones With A Unique Substitution Pattern

dc.creatorGuidotti
dc.creatorBruno B.; Coelho
dc.creatorFernando
dc.date2015-Nov
dc.date2016-06-07T13:18:26Z
dc.date2016-06-07T13:18:26Z
dc.date.accessioned2018-03-29T01:38:46Z
dc.date.available2018-03-29T01:38:46Z
dc.identifier
dc.identifierSequential Morita-baylis-hillman/achmatowicz Reactions: An Expeditious Access To Pyran-3(6h)-ones With A Unique Substitution Pattern. Pergamon-elsevier Science Ltd, v. 56, p. 6356-6359 Nov-2015.
dc.identifier0040-4039
dc.identifierWOS:000364436300012
dc.identifier10.1016/j.tetlet.2015.09.120
dc.identifierhttp://www.sciencedirect.com/science/article/pii/S0040403915301635
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/242496
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1306194
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.descriptionWe herein disclosed a novel approach to synthesize densely functionalized 6-hydroxy-2H-pyran-3(6H)-ones with moderate to good diastereoselectivity. The method is based on a two step sequence using Morita-Baylis-Hillman adducts as substrates for the Achmatowicz rearrangement, allowing the preparation of highly substituted pyran-3-ones with overall yields ranging from 17% to 80% and a unique substitution pattern. (C) 2015 Elsevier Ltd. All rights reserved.
dc.description56
dc.description46
dc.description
dc.description6356
dc.description6359
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.descriptionFAPESP [2013/07600-3, 2013/10449-5]
dc.descriptionCNPq [307840/2014-0]
dc.description
dc.description
dc.description
dc.languageen
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD
dc.publisher
dc.publisherOXFORD
dc.relationTETRAHEDRON LETTERS
dc.rightsembargo
dc.sourceWOS
dc.subjectStereoselective Total-synthesis
dc.subjectNovo Asymmetric-synthesis
dc.subjectHillman Reaction
dc.subjectEnantioselective Synthesis
dc.subjectAchmatowicz Reaction
dc.subject(+)-phomopsolide B
dc.subjectFuran-derivatives
dc.subjectOrganic-synthesis
dc.subjectCross-metathesis
dc.subjectGeneral-approach
dc.titleSequential Morita-baylis-hillman/achmatowicz Reactions: An Expeditious Access To Pyran-3(6h)-ones With A Unique Substitution Pattern
dc.typeArtículos de revistas


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