Highly Regio- And Stereoselective Heck Reaction Of Allylic Esters With Arenediazonium Salts: Application To The Synthesis Of Kavalactones.

dc.creatorMoro, Angélica Venturini
dc.creatorCardoso, Flávio Sega Pereira
dc.creatorCorreia, Carlos Roque Duarte
dc.date2009-Aug
dc.date2015-11-27T13:15:31Z
dc.date2015-11-27T13:15:31Z
dc.date.accessioned2018-03-29T01:09:21Z
dc.date.available2018-03-29T01:09:21Z
dc.identifierOrganic Letters. v. 11, n. 16, p. 3642-5, 2009-Aug.
dc.identifier1523-7052
dc.identifier10.1021/ol901416e
dc.identifierhttp://www.ncbi.nlm.nih.gov/pubmed/19719201
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/198452
dc.identifier19719201
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1298685
dc.descriptionA highly efficient palladium-catalyzed Heck reaction of allylic esters with arenediazonium salts is described. The reaction proceeds under mild conditions, with excellent to total regio- and stereochemical control and with retention of the traditional leaving group. Furthermore, the generality of the present methodology is illustrated by the short total synthesis of the natural kavalactones, yangonine, (+/-)-methysticin, and (+/-)-dihydromethysticin.
dc.description11
dc.description3642-5
dc.languageeng
dc.relationOrganic Letters
dc.relationOrg. Lett.
dc.rightsfechado
dc.rights
dc.sourcePubMed
dc.titleHighly Regio- And Stereoselective Heck Reaction Of Allylic Esters With Arenediazonium Salts: Application To The Synthesis Of Kavalactones.
dc.typeArtículos de revistas


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