A Highly Sensitive Amperometric Sensor For Oxygen Based On Iron(ii) Tetrasulfonated Phthalocyanine And Iron(iii) Tetra-(n-methyl-pyridyl)-porphyrin Multilayers.

dc.creatorDuarte, Juliana C
dc.creatorLuz, Rita C S
dc.creatorDamos, Flavio S
dc.creatorTanaka, Auro A
dc.creatorKubota, Lauro T
dc.date2008-Mar
dc.date2015-11-27T13:12:35Z
dc.date2015-11-27T13:12:35Z
dc.date.accessioned2018-03-29T01:06:25Z
dc.date.available2018-03-29T01:06:25Z
dc.identifierAnalytica Chimica Acta. v. 612, n. 1, p. 29-36, 2008-Mar.
dc.identifier1873-4324
dc.identifier10.1016/j.aca.2008.02.001
dc.identifierhttp://www.ncbi.nlm.nih.gov/pubmed/18331855
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/197705
dc.identifier18331855
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1297938
dc.descriptionThe development of a highly sensitive sensor for oxygen is proposed using a glassy carbon (GC) electrode modified with alternated layers of iron(II) tetrasulfonated phthalocyanine (FeTsPc) and iron(III) tetra-(N-methyl-pyridyl)-porphyrin (FeT4MPyP). The modified electrode showed excellent catalytic activity for the oxygen reduction. The reduction potential of the oxygen was shifted about 330 mV toward less negative values with this modified electrode, presenting a peak current much higher than those observed on a bare GC electrode. Cyclic voltammetry and rotating disk electrode (RDE) experiments indicated that the oxygen reduction reaction involves 4 electrons with a heterogenous rate constant (k(obs)) of 3x10(5) mol(-1) L s(-1). A linear response range from 0.2 up to 6.4 mg L(-1), with a sensitivity of 4.12 microA L mg(-1) (or 20.65 microA cm(-2) L mg(-1)) and a detection limit of 0.06 mg L(-1) were obtained with this sensor. The repeatability of the proposed sensor, evaluated in terms of relative standard deviation (R.S.D.) was 2.0% for 10 measurements of a solution of 6.4 mg L(-1) oxygen. The sensor was applied to determine oxygen in pond and tap water samples showing to be a promising tool for this purpose.
dc.description612
dc.description29-36
dc.languageeng
dc.relationAnalytica Chimica Acta
dc.relationAnal. Chim. Acta
dc.rightsfechado
dc.rights
dc.sourcePubMed
dc.titleA Highly Sensitive Amperometric Sensor For Oxygen Based On Iron(ii) Tetrasulfonated Phthalocyanine And Iron(iii) Tetra-(n-methyl-pyridyl)-porphyrin Multilayers.
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución