dc.creatorRamos Catharino, Rodrigo
dc.creatorde Azevedo Marques, Lygia
dc.creatorSilva Santos, Leonardo
dc.creatorBaptista, Antonio S
dc.creatorGlória, Eduardo M
dc.creatorCalori-Domingues, Maria A
dc.creatorFacco, Elizete M P
dc.creatorEberlin, Marcos N
dc.date2005-Dec
dc.date2015-11-27T13:02:38Z
dc.date2015-11-27T13:02:38Z
dc.date.accessioned2018-03-29T01:01:49Z
dc.date.available2018-03-29T01:01:49Z
dc.identifierAnalytical Chemistry. v. 77, n. 24, p. 8155-7, 2005-Dec.
dc.identifier0003-2700
dc.identifier10.1021/ac051111p
dc.identifierhttp://www.ncbi.nlm.nih.gov/pubmed/16351169
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/196514
dc.identifier16351169
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1296747
dc.descriptionEfficient detection of aflatoxins B1, B2, G1, and G2 has been performed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry using a UV-absorbing ionic liquid matrix to obtain matrix-free mass spectra and addition of NaCl to enhance sensitivity via Na+ cationization. Using ionic alpha-cyano-4-hydroxycinnamic acid (Et3N-alpha-CHCA) as the matrix, matrix-free mass spectra in the m/z range of interest are acquired, and the B1, B2, G1, and G2 aflatoxins are readily detected with an LOD as low as 50 fmol. The technique is fast, requires little sample preparation and no derivatization or chromatographic separation, and seems therefore to be suitable for high-throughput aflatoxin screening. It should be easily extended to other micotoxins and provide an attractive technique to control the quality of major crops subjected to huge world commercial trades such as peanuts, corn, and rice as well as to monitor bioterrorism threats by micotoxin poisoning.
dc.description77
dc.description8155-7
dc.languageeng
dc.relationAnalytical Chemistry
dc.relationAnal. Chem.
dc.rightsfechado
dc.rights
dc.sourcePubMed
dc.subjectAflatoxins
dc.subjectArachis Hypogaea
dc.subjectFood Contamination
dc.subjectSpectrometry, Mass, Matrix-assisted Laser Desorption-ionization
dc.titleAflatoxin Screening By Maldi-tof Mass Spectrometry.
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución