Estimate of Delta(D) H-m(o) for adducts by thermogravimetry.

dc.creatorde Farias, RF
dc.date1998
dc.dateJUL-AUG
dc.date2014-12-02T16:27:41Z
dc.date2015-11-26T18:07:57Z
dc.date2014-12-02T16:27:41Z
dc.date2015-11-26T18:07:57Z
dc.date.accessioned2018-03-29T00:50:04Z
dc.date.available2018-03-29T00:50:04Z
dc.identifierQuimica Nova. Soc Brasileira Quimica, v. 21, n. 4, n. 437, n. 440, 1998.
dc.identifier0100-4042
dc.identifierWOS:000074730600011
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/65611
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/65611
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/65611
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1293708
dc.descriptionAn empirical equation: Delta(D)H(m)(O) = t(i)/2.2(2-n) is obtained and tested for 102 adducts (mainly adducts with zinc group halides). In the equation, t(i) is the Kelvin temperature of the beginning of the thermal decomposition of the adduct, (obtained by thermogravimetry), and n is the number of ligands. For 1/3 of the tested adducts the difference between experimental and calculated values was less than 5%. For about 1/3 of the adducts that difference exceeds 15%.
dc.description21
dc.description4
dc.description437
dc.description440
dc.languagept
dc.publisherSoc Brasileira Quimica
dc.publisherSao Paulo
dc.publisherBrasil
dc.relationQuimica Nova
dc.relationQuim. Nova
dc.rightsaberto
dc.sourceWeb of Science
dc.subjectadducts
dc.subjectthermochemical parameters
dc.subjectempirical equation
dc.subjectthermogravimetry
dc.subjectZinc
dc.titleEstimate of Delta(D) H-m(o) for adducts by thermogravimetry.
dc.typeArtículos de revistas


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