Effect of Initiator Type and Concentration on Polymerization Rate and Molecular Weight in the Bimolecular Nitroxide-Mediated Radical Polymerization of Styrene

dc.creatorNogueira, TR
dc.creatorGoncalves, MC
dc.creatorLona, LMF
dc.creatorVivaldo-Lima, E
dc.creatorMcManus, N
dc.creatorPenlidis, A
dc.date2010
dc.dateSPR
dc.date2014-11-13T11:38:19Z
dc.date2015-11-26T18:07:05Z
dc.date2014-11-13T11:38:19Z
dc.date2015-11-26T18:07:05Z
dc.date.accessioned2018-03-29T00:49:13Z
dc.date.available2018-03-29T00:49:13Z
dc.identifierAdvances In Polymer Technology. John Wiley & Sons Inc, v. 29, n. 1, n. 11, n. 19, 2010.
dc.identifier0730-6679
dc.identifierWOS:000277805600002
dc.identifier10.1002/adv.20170
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/64431
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/64431
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/64431
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1293504
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionTo increase the polymerization rate in the bimolecular nitroxide-mediated radical polymerization (NMRP) of styrene, without using expensive non-commercial reagents, an experimental study using 2,2,6,6-tetramethyl-1-piperidinoxyl as a controller and tert-butylperoxy 2-ethylhexyl carbonate (TBEC) as the initiator was carried out. The basis for comparison was the bimolecular NMRP of styrene with dibenzoyl peroxide as initiator. It was found that faster polymerization rates and still relatively low polydispersities were possible using TBEC. (C) 2010 Wiley Periodicals, Inc. Ads' Polym Techn 29: 11-19, 2010; Published online in Wiley Inter Science (www.interscience.wileycom). DOT 10.1002/adv.20170
dc.description29
dc.description1
dc.description11
dc.description19
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionNational Council for Scientific and Technological Development (CNN) (Brazil)
dc.descriptionConsejo Nacional de Ciencia y Tecnologia (CONACYT) (Mexico) [CIAM U40259-Y, CB101682]
dc.descriptionNatural Sciences and Engineering Research Council of Canada (NSERC/CRO)
dc.descriptionCanada Research Chair (CRC) Program (Canada)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConsejo Nacional de Ciencia y Tecnologia (CONACYT) (Mexico) [CIAM U40259-Y, CB101682]
dc.languageen
dc.publisherJohn Wiley & Sons Inc
dc.publisherHoboken
dc.publisherEUA
dc.relationAdvances In Polymer Technology
dc.relationAdv. Polym. Technol.
dc.rightsfechado
dc.rightshttp://olabout.wiley.com/WileyCDA/Section/id-406071.html
dc.sourceWeb of Science
dc.subjectKinetics (polym.)
dc.subjectLiving polymerization
dc.subjectPolystyrene
dc.subjectRadical polymerization
dc.subjectN-butyl Acrylate
dc.subjectRate Enhancement
dc.subjectMiniemulsion Polymerization
dc.subjectAcetic-anhydride
dc.subjectAcid
dc.subjectPolydispersity
dc.subjectSimulation
dc.subjectKinetics
dc.titleEffect of Initiator Type and Concentration on Polymerization Rate and Molecular Weight in the Bimolecular Nitroxide-Mediated Radical Polymerization of Styrene
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución