Efficient Catalysis of Aqueous Morita-Baylis-Hillman Reactions of Cyclic Enones by a Bicyclic Imidazolyl Alcohol

dc.creatorGomes, JC
dc.creatorRodrigues, MT
dc.creatorMoyano, A
dc.creatorCoelho, F
dc.date2012
dc.dateDEC
dc.date2014-08-01T18:30:28Z
dc.date2015-11-26T18:05:50Z
dc.date2014-08-01T18:30:28Z
dc.date2015-11-26T18:05:50Z
dc.date.accessioned2018-03-29T00:48:06Z
dc.date.available2018-03-29T00:48:06Z
dc.identifierEuropean Journal Of Organic Chemistry. Wiley-v C H Verlag Gmbh, n. 35, n. 6861, n. 6866, 2012.
dc.identifier1434-193X
dc.identifierWOS:000312035900006
dc.identifier10.1002/ejoc.201200950
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/79941
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/79941
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1293228
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionIn this paper a new phosphorus-free catalyst for the Morita-Baylis-Hillman reaction is disclosed. A bicyclic imidazolyl alcohol having a Lewis basic center associated with a hydrogen-bond donor group was used as catalyst for the reaction. Aliphatic cycloalkanones such as 2-cyclopentenone and 2-cyclohexanone and aliphatic and aromatic aldehydes were used successfully, and the reaction was found to work nicely using water as solvent in the presence of a phase-transfer additive.
dc.description35
dc.description6861
dc.description6866
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionMinisterio de Ciencia e Innovacion (MICINN) [AYA2009-13920-C02-02]
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionMinisterio de Ciencia e Innovacion (MICINN) [AYA2009-13920-C02-02]
dc.languageen
dc.publisherWiley-v C H Verlag Gmbh
dc.publisherWeinheim
dc.publisherAlemanha
dc.relationEuropean Journal Of Organic Chemistry
dc.relationEur. J. Org. Chem.
dc.rightsfechado
dc.rightshttp://olabout.wiley.com/WileyCDA/Section/id-406071.html
dc.sourceWeb of Science
dc.subjectOrganocatalysis
dc.subjectSynthetic methods
dc.subjectHeterocycles
dc.subjectAldehydes
dc.subjectKetones
dc.subjectOne-pot Synthesis
dc.subjectDiaryliodonium Salts
dc.subjectAryl Thiocyanates
dc.subjectBond Formation
dc.subjectMetal-free
dc.subjectSulfides
dc.subjectArylation
dc.subjectInhibitors
dc.subjectEpoxides
dc.subjectThiols
dc.titleEfficient Catalysis of Aqueous Morita-Baylis-Hillman Reactions of Cyclic Enones by a Bicyclic Imidazolyl Alcohol
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución