An alternative synthetic access to cis-4a-Methyloctahydrophenanthrene, a biomarker of Sergipe-Alagoas Basin petroleum in Brazil

dc.creatorRodrigues, DC
dc.creatorde Meijere, A
dc.creatorMarsaioli, AJ
dc.date2002
dc.dateSEP-OCT
dc.date2014-11-19T17:55:38Z
dc.date2015-11-26T18:04:55Z
dc.date2014-11-19T17:55:38Z
dc.date2015-11-26T18:04:55Z
dc.date.accessioned2018-03-29T00:47:07Z
dc.date.available2018-03-29T00:47:07Z
dc.identifierJournal Of The Brazilian Chemical Society. Soc Brasileira Quimica, v. 13, n. 5, n. 664, n. 668, 2002.
dc.identifier0103-5053
dc.identifierWOS:000178769700019
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/54295
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/54295
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/54295
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1292980
dc.descriptioncis-4a-Methyloctahydrophenanthrene (1) was prepared in 8 steps (23% overall yield) from 2-bromophenyl)acetic acid (3) and cyclohexane-1,3-dione (6). A highly cis-diastereoselective Michael-type Heck coupling served as the key step in the assembly of the tricyclic skeleton. This compound 1 was used as gas chromatography standard which allowed the unequivocal identification of a minor biomarker present in Carmopolis oil from the Sergipe-Alagoas Basin in Brazil.
dc.description13
dc.description5
dc.description664
dc.description668
dc.languageen
dc.publisherSoc Brasileira Quimica
dc.publisherSao Paulo
dc.publisherBrasil
dc.relationJournal Of The Brazilian Chemical Society
dc.relationJ. Braz. Chem. Soc.
dc.rightsaberto
dc.sourceWeb of Science
dc.subjectcis-4a-Methyloctahydrophenanthrene
dc.subjectbiomarker
dc.subjectCarmopolis petroleum
dc.subjectSergipe-Alagoas Basin
dc.subjectPalladium-catalyzed Vinylation
dc.subjectMarine Evaporitic Oils
dc.subjectStereoselective Synthesis
dc.subjectSubstituted Series
dc.subjectCampos Basin
dc.subject4a-methyloctahydrophenanthrenes
dc.subjectHalides
dc.subjectArylation
dc.subjectSystem
dc.subjectAcids
dc.titleAn alternative synthetic access to cis-4a-Methyloctahydrophenanthrene, a biomarker of Sergipe-Alagoas Basin petroleum in Brazil
dc.typeArtículos de revistas


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