dc.creatorBASSO, EA
dc.creatorKAISER, C
dc.creatorRITTNER, R
dc.creatorLAMBERT, JB
dc.date1993
dc.dateDEC 31
dc.date2014-12-16T11:34:25Z
dc.date2015-11-26T18:01:11Z
dc.date2014-12-16T11:34:25Z
dc.date2015-11-26T18:01:11Z
dc.date.accessioned2018-03-29T00:42:42Z
dc.date.available2018-03-29T00:42:42Z
dc.identifierJournal Of Organic Chemistry. Amer Chemical Soc, v. 58, n. 27, n. 7865, n. 7869, 1993.
dc.identifier0022-3263
dc.identifierWOS:A1993MQ57300035
dc.identifier10.1021/jo00079a035
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/55253
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/55253
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/55253
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1291913
dc.descriptionAxial-equatorial conformational proportions have been measured for 2-substituted cyclohexanones in chloroform by the Eliel method for F, Cl, Br, I, MeO, MeS, Me2N, MeSe, and Me. For the first seven of these, at least five experimentally independent measurables were used and the resulting conformational preferences appear to be accurate to within 10%. Systematic errors degraded the results for MeSe and Me. For Me2N, the conformational preference also was measured for the first time at slow exchange in the low-temperature C-13 spectrum in several solvents. In chloroform, steric and polar effects contribute to the conformational preferences, with steric effects dominant for large groups such as I and MeS.
dc.description58
dc.description27
dc.description7865
dc.description7869
dc.languageen
dc.publisherAmer Chemical Soc
dc.publisherWashington
dc.relationJournal Of Organic Chemistry
dc.relationJ. Org. Chem.
dc.rightsfechado
dc.sourceWeb of Science
dc.subjectCarbonyl-compounds
dc.subjectTert-alkylation
dc.subjectKetones
dc.subjectAldehydes
dc.titleAXIAL EQUATORIAL PROPORTIONS FOR 2-SUBSTITUTED CYCLOHEXANONES
dc.typeArtículos de revistas


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