| dc.creator | Carvalho, WA | |
| dc.creator | Varaldo, PB | |
| dc.creator | Wallau, M | |
| dc.creator | Schuchardt, U | |
| dc.date | 1997 | |
| dc.date | MAY-JUN | |
| dc.date | 2014-12-16T11:32:03Z | |
| dc.date | 2015-11-26T17:50:25Z | |
| dc.date | 2014-12-16T11:32:03Z | |
| dc.date | 2015-11-26T17:50:25Z | |
| dc.date.accessioned | 2018-03-29T00:33:39Z | |
| dc.date.available | 2018-03-29T00:33:39Z | |
| dc.identifier | Zeolites. Elsevier Science Inc, v. 18, n. 41795, n. 408, n. 416, 1997. | |
| dc.identifier | 0144-2449 | |
| dc.identifier | WOS:A1997XK61200014 | |
| dc.identifier | 10.1016/S0144-2449(97)00031-6 | |
| dc.identifier | http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/53614 | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/53614 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/53614 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1289678 | |
| dc.description | The synthesis of MCM-41 analogue mesoporous metallosilicates with high specific surfaces, containing the redox active metals Ti, V, Cr, Mn, Fe, or Co, from an aqueous gel, under reflux is described. Their X-ray diffractograms reveal a highly ordered array of the mesopores. A strong host-guest interaction between the incorporated template molecules and the pore walls, observed by C-13 n.m.r., indicates the incorporation of the metals, which is further evidenced by u.v.-vis and Si-29 n.m.r. spectroscopy. These mesoporous metallosilicates are active as catalysts for the liquid phase oxidation of cyclohexane with aqueous H2O2 or tert-butyl hydroperoxide. (C) Elsevier Science Inc. 1997. | |
| dc.description | 18 | |
| dc.description | 41795 | |
| dc.description | 408 | |
| dc.description | 416 | |
| dc.language | en | |
| dc.publisher | Elsevier Science Inc | |
| dc.publisher | New York | |
| dc.relation | Zeolites | |
| dc.relation | Zeolites | |
| dc.rights | fechado | |
| dc.rights | http://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy | |
| dc.source | Web of Science | |
| dc.subject | mesoporous metallosilicates | |
| dc.subject | MCM-41 | |
| dc.subject | redox molecular sieves | |
| dc.subject | synthesis | |
| dc.subject | spectroscopic characterization | |
| dc.subject | liquid phase oxidation of cyclohexane | |
| dc.subject | Catalytic-oxidation | |
| dc.subject | Zeolites | |
| dc.subject | Titanium | |
| dc.subject | Spectroscopy | |
| dc.subject | Silicalite | |
| dc.subject | Ions | |
| dc.title | Mesoporous redox molecular sieves analogous to MCM-41 | |
| dc.type | Artículos de revistas | |
