Highly Regio- and Stereoselective Heck Reaction of Allylic Esters with Arenediazonium Salts: Application to the Synthesis of Kavalactones

dc.creatorMoro, AV
dc.creatorCardoso, FSP
dc.creatorCorreia, CRD
dc.date2009
dc.dateAUG 20
dc.date2014-11-18T11:22:42Z
dc.date2015-11-26T17:49:53Z
dc.date2014-11-18T11:22:42Z
dc.date2015-11-26T17:49:53Z
dc.date.accessioned2018-03-29T00:33:00Z
dc.date.available2018-03-29T00:33:00Z
dc.identifierOrganic Letters. Amer Chemical Soc, v. 11, n. 16, n. 3642, n. 3645, 2009.
dc.identifier1523-7060
dc.identifierWOS:000268796700031
dc.identifier10.1021/ol901416e
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/68419
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/68419
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/68419
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1289511
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionA highly efficient palladium-catalyzed Heck reaction of allylic esters with arenediazonium salts is described. The reaction proceeds under mild conditions, with excellent to total regio- and stereochemical control and with retention of the traditional leaving group. Furthermore, the generality of the present methodology is illustrated by the short total synthesis of the natural kavalactones, yangonine, (+/-)-methysticin, and (+/-)-dihydromethysticin.
dc.description11
dc.description16
dc.description3642
dc.description3645
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFAPESP [05/05150-4, 07/03033-6]
dc.descriptionCNPq [308320/2006-9]
dc.languageen
dc.publisherAmer Chemical Soc
dc.publisherWashington
dc.publisherEUA
dc.relationOrganic Letters
dc.relationOrg. Lett.
dc.rightsfechado
dc.sourceWeb of Science
dc.subjectPalladium-catalyzed Arylation
dc.subjectKava-kava
dc.subjectCarbonyl-compounds
dc.subjectPiper-methysticum
dc.subjectCinnamyl Alcohols
dc.subjectDiazonium Salts
dc.subjectIodonium Salts
dc.subjectIonic Liquids
dc.subjectAryl Bromides
dc.subjectMethyl-ester
dc.titleHighly Regio- and Stereoselective Heck Reaction of Allylic Esters with Arenediazonium Salts: Application to the Synthesis of Kavalactones
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución