Artículos de revistas
STANDARD MOLAR ENTHALPIES OF SOLVATION OF ALIPHATIC ESTERS IN 1,2-DICHLOROETHANE AND N-HEXANE
Journal Of Solution Chemistry. Plenum Publ Corp, v. 22, n. 8, n. 707, n. 713, 1993.
The molar enthalpies of solution at infinite dilution of methyl-, ethyl-, n-butyl- and n-pentylacetate, and ethylpropionate, ethylbutanoate and ethylhexanoate were obtained by means of calorimetric determinations in 1,2-dichloroethane and n-hexane. From these values and the standard molar enthalpy of vaporization, the standard molar enthalpy of solvation of these esters in both solvents were calculated. These calculated values are shown to correlate with the number of methylene groups in the esters.228707713