Artículos de revistas
STANDARD MOLAR ENTHALPIES OF SOLVATION OF ALIPHATIC ESTERS IN 1,2-DICHLOROETHANE AND N-HEXANE
Registro en:
Journal Of Solution Chemistry. Plenum Publ Corp, v. 22, n. 8, n. 707, n. 713, 1993.
0095-9782
WOS:A1993LU45100003
10.1007/BF00647410
Autor
AIROLDI, C
ROCA, S
Institución
Resumen
The molar enthalpies of solution at infinite dilution of methyl-, ethyl-, n-butyl- and n-pentylacetate, and ethylpropionate, ethylbutanoate and ethylhexanoate were obtained by means of calorimetric determinations in 1,2-dichloroethane and n-hexane. From these values and the standard molar enthalpy of vaporization, the standard molar enthalpy of solvation of these esters in both solvents were calculated. These calculated values are shown to correlate with the number of methylene groups in the esters. 22 8 707 713