Modeling aluminum-silicon chemistries and application to Australian acidic playa lakes as analogues for Mars

dc.creatorMarion, GM
dc.creatorCrowley, JK
dc.creatorThomson, BJ
dc.creatorKargel, JS
dc.creatorBridges, NT
dc.creatorHook, SJ
dc.creatorBaldridge, A
dc.creatorBrown, AJ
dc.creatorda Luz, BR
dc.creatorde Souza, CR
dc.date2009
dc.date37043
dc.date2014-11-18T09:45:53Z
dc.date2015-11-26T17:49:03Z
dc.date2014-11-18T09:45:53Z
dc.date2015-11-26T17:49:03Z
dc.date.accessioned2018-03-29T00:32:04Z
dc.date.available2018-03-29T00:32:04Z
dc.identifierGeochimica Et Cosmochimica Acta. Pergamon-elsevier Science Ltd, v. 73, n. 11, n. 3493, n. 3511, 2009.
dc.identifier0016-7037
dc.identifier1872-9533
dc.identifierWOS:000266059700024
dc.identifier10.1016/j.gca.2009.03.013
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/82468
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/82468
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/82468
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1289290
dc.descriptionRecent Mars missions have stimulated considerable thinking about the surficial geochemical evolution of Mars. Among the major relevant findings are the presence in Meridiani Planum sediments of the mineral jarosite (a ferric sulfate salt) and related minerals that require formation from all acid-salt brine and oxidizing environment. Similar mineralogies have been observed in acidic saline lake sediments in Western Australia (WA), and these lakes have been proposed as analogues for acidic sedimentary environments oil Mars. The prior version of the equilibrium chemical thermodynamic FREZCHEM model lacked Al and Si chemistries that are needed to appropriately model acidic aqueous geochemistries oil Earth and Mars. The objectives of this work were to (1) add Al and Si chemistries to the FREZCHEM model, (2) extend these chemistries to low temperatures (<0 degrees C), if possible, and (3) use the reformulated model to investigate parallels in the mineral precipitation behavior of acidic Australian lakes and hypothetical Martian brines. FREZCHEM is an equilibrium chemical thermodynamic model parameterized for concentrated electrolyte solutions using the Pitzer approach for the temperature range from <-70 to 25 degrees C and the pressure range from I to 1000 bars. Aluminum chloride and sulfate mineral parameterizations were based oil experimental data. Aluminum hydroxide and silicon mineral parameterizations were based oil Gibbs free energy and enthalpy data. New aluminum and silicon parameterizations added 12 new aluminum/silicon minerals to this Na-K-Mg-Ca-Fe(II)-Fe(III)-Al-H-Cl-Br-SO4-NO3-OH-HCO3-CO3-CO2-O-2-CH4-Si-H2O system that now contain 95 solid phases. There were similarities, differences, and uncertain ties between Australian acidic, saline playa lakes and waters that likely led to the Burns formation salt accumulations oil Mars. Both systems are similar in that they are dominated by ( 1) acidic, saline ground waters and sediments, (2) Ca apointing to the dominant influence of ground water chemistry, vertical such lateral variations are much less pronounced.nd/or Mg sulfates, and (3) iron precipitates Such as jarosite and hematite. Differences include: (1) the dominance of NaCl in many WA lakes, versus the dominance of Fe-Mg-Ca-SO4 in Meridiani Planum, (2) excessively low K+ concentrations in Meridiani Planum due to jarosite precipitation, (3) higher acid production in the presence of high iron concentrations in Meridiani Planum, and probably lower rates of acid neutralization and hence, higher acidities oil Mars owing to colder temperatures, and (4) lateral salt patterns in WA lakes. The WA playa lakes display significant lateral variations in mineralogy and water chemistry over short distances, reflecting the interaction of acid ground waters with neutral to alkaline lake waters derived from ponded surface runoff. Meridiani Planum observations indicate that such lateral variations are much less pronounced, pointing to the dominant influence of ground water chemistry, vertical ground water movements, and aeolian processes on the Martian surface mineralogy. (C) 2009 Elsevier Ltd. All rights reserved.
dc.description73
dc.description11
dc.description3493
dc.description3511
dc.languageen
dc.publisherPergamon-elsevier Science Ltd
dc.publisherOxford
dc.publisherInglaterra
dc.relationGeochimica Et Cosmochimica Acta
dc.relationGeochim. Cosmochim. Acta
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectRio-tinto Basin
dc.subjectMeridiani-planum
dc.subjectOmega/mars Express
dc.subjectLow-temperatures
dc.subjectMossbauer Spectrometer
dc.subjectThermodynamic Model
dc.subjectTerrestrial Analogs
dc.subjectWestern-australia
dc.subjectBurns Formation
dc.subjectIron Chemistry
dc.titleModeling aluminum-silicon chemistries and application to Australian acidic playa lakes as analogues for Mars
dc.typeArtículos de revistas


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