Enantioselective synthesis of alpha-hydroxysilanes by bioreduction of aroyltrimethylsilanes

dc.creatorPatrocinio, AF
dc.creatorCorrea, IR
dc.creatorMoran, PJS
dc.date1999
dc.date39387
dc.date2014-12-02T16:31:02Z
dc.date2015-11-26T17:41:26Z
dc.date2014-12-02T16:31:02Z
dc.date2015-11-26T17:41:26Z
dc.date.accessioned2018-03-29T00:23:14Z
dc.date.available2018-03-29T00:23:14Z
dc.identifierJournal Of The Chemical Society-perkin Transactions 1. Royal Soc Chemistry, n. 21, n. 3133, n. 3137, 1999.
dc.identifier0300-922X
dc.identifierWOS:000085587900015
dc.identifier10.1039/a906335h
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/64729
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/64729
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/64729
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1287011
dc.descriptionAromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5, 4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)(2)C6H5 and 3,4-OCH2OC6H3] were reduced by baker's yeast to optically active alpha-silyl alcohols in 20-70% yield and 43-88% ee. Comments are made on the influence of silicon in this bioreduction reaction.
dc.description21
dc.description3133
dc.description3137
dc.languageen
dc.publisherRoyal Soc Chemistry
dc.publisherCambridge
dc.publisherInglaterra
dc.relationJournal Of The Chemical Society-perkin Transactions 1
dc.relationJ. Chem. Soc.-Perkin Trans. 1
dc.rightsaberto
dc.sourceWeb of Science
dc.subjectBakers-yeast
dc.subjectSecondary Alcohols
dc.subjectAcyl Silanes
dc.subjectReduction
dc.subjectAcylsilanes
dc.subjectRearrangement
dc.subjectStep
dc.titleEnantioselective synthesis of alpha-hydroxysilanes by bioreduction of aroyltrimethylsilanes
dc.typeArtículos de revistas


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