Artículos de revistas
Addition of silylated carbon nucleophiles to iminium and cyclic N-acyliminium ions promoted by InCl3
Registro en:
Tetrahedron Letters. Pergamon-elsevier Science Ltd, v. 41, n. 51, n. 9939, n. 9942, 2000.
0040-4039
WOS:000165960100003
10.1016/S0040-4039(00)01828-1
Autor
Russowsky, D
Petersen, RZ
Godoi, MN
Pilli, RA
Institución
Resumen
InCl3 was used as Lewis acid in the addition of silyl enolates and allyltrimethylsilane to aromatic aldimines and cyclic N-acyliminium ions derived from 5-acetoxylactams affording beta -aminocarbonyl systems and allyl adducts, respectively, in reasonable to good yields. The diastereofacial selectivity of cyclic N-acyliminium ions was investigated. (C) 2000 Elsevier Science Ltd. All rights reserved. 41 51 9939 9942